2,2,3,3-Tetramethyl-1,4-dioxaspiro[4.5]dec-6-en-8-one | 1123219-08-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 2,2,3,3-Tetramethyl-1,4-dioxaspiro[4.5]dec-6-en-8-one
• CAS: 1123219-08-8
• 化学式: C₁₂H₁₈O₃
• 分子量: 210.273
• InChiKey: YAYAXUVJKUHTJO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.1
• 重原子数：
  15
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  3

文献信息

• PROCESS FOR PREPARATION OF CARBONYL COMPOUND AND PRO-OXIDANT FOR PREPARATION OF CARBONYL COMPOUND
  申请人：Ishihara Kazuaki

  公开号：US20100041917A1

  公开（公告）日：2010-02-18

  The invention provides a process for the preparation of a carbonyl compound in high efficiency by oxidizing an alcohol. The process for the preparation of a carbonyl compound of the present invention includes a step of oxidizing an alcohol in the presence of a compound of the formula (I) or a derivative or a salt thereof, and an oxidant, wherein R 1 and R 2 independently represent hydrogen, a halogen, a nitro or acidic group, or an alkyl or alkoxy group, each of which optionally has a substituent, or R 1 and R 2 combine the two carbon atoms to which they are boned to form an aromatic ring.

  本发明提供了一种通过氧化醇类化合物高效制备羰基化合物的方法。本发明的制备羰基化合物的方法包括在化合物(I)的衍生物或盐及氧化剂的存在下氧化醇类化合物的步骤，其中R1和R2分别独立地表示氢、卤素、硝基或酸性基团或烷基或烷氧基，每个基团可选地具有取代基，或者R1和R2结合形成它们所结合的两个碳原子形成芳环。
• METHOD FOR PRODUCING CARBONYL COMPOUND AN PRO-OXIDANT USED FOR PRODUCTION OF CARBONYL COMPOUND
  申请人：National University Corporation Nagoya University

  公开号：EP2085373A1

  公开（公告）日：2009-08-05

  The invention provides a process for the preparation of a carbonyl compound in high efficiency by oxidizing an alcohol. The process for the preparation of a carbonyl compound of the present invention includes a step of oxidizing an alcohol in the presence of a compound of the formula (I) or a derivative or a salt thereof, and an oxidant, wherein R1 and R2 independently represent hydrogen, a halogen, a nitro or acidic group, or an alkyl or alkoxy group, each of which optionally has a substituent, or R1 and R2 combine the two carbon atoms to which they are boned to form an aromatic ring.

  本发明提供了一种通过氧化醇高效制备羰基化合物的工艺。本发明制备羰基化合物的工艺包括在式（I）化合物或其衍生物或盐以及氧化剂存在下氧化醇的步骤、 其中 R1 和 R2 独立地代表氢、卤素、硝基或酸性基团，或烷基或烷氧基，每个基团可选地具有一个取代基，或 R1 和 R2 将它们所骨架的两个碳原子结合成一个芳香环。
• US8394995B2
  申请人：——

  公开号：US8394995B2

  公开（公告）日：2013-03-12