3-ethoxycyclopentene | 20657-23-2

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 3-ethoxycyclopentene
• 英文别名: ethyl-cyclopent-2-enyl ether；Aethyl-cyclopent-2-enyl-aether；3-Aethoxy-cyclopenten
• CAS: 20657-23-2
• 化学式: C₇H₁₂O
• 分子量: 112.172
• InChiKey: BBASYDDNIRBDJJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.5
• 重原子数：
  8
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  3-ethoxycyclopentene 生成 trans-2-(ethoxy)cyclopentanol
  参考文献：
  名称：

  Hydroboration. XXVIII. The hydroboration of 3-cyclopentenyl derivatives containing representative substituents. Directive effects and the elimination reaction in a cyclic system

  摘要：

  DOI：

  10.1021/ja01018a042
• 作为产物：
  描述：

  乙醇 、 cyclopent-2-en-1-yl 4-nitrobenzoate 以 水 为溶剂， 生成 3-ethoxycyclopentene
  参考文献：
  名称：

  Kopecky, Karl R.; Levine, Cyril, Canadian Journal of Chemistry, 1981, vol. 59, p. 3273 - 3279

  摘要：

  DOI：

文献信息

• Palladium-catalyzed intermolecular Arylation of functionally-Substituted Cycloalkenes by Aryl Iodides
  作者：Richard C. Larock、Eut K. Yum、Hoseok Yang

  DOI：10.1016/s0040-4020(01)80756-0

  日期：1994.1

  products. 1-Acetoxycyclopentene undergoes arylation to produce the corresponding allylic aryl substitution product opening up a new route for the α-arylation of cycloalkanones. Cyclic allylic ethers undergo arylation at both ends of the C-C double bond to generate mixtures of singly arylated vinylic ethers. 1-Cyanocyclopentene reacts with aryl iodides under palladium catalysis to produce 1-cyano-5-arylcyclopentenes

  芳基碘化物对功能性取代的环烯烃进行钯催化的分子间芳基化为各种芳基化的环状衍生物提供了一条新的合成途径。2-环戊烯-1-醇和2-环己烯-1-醇的芳基化反应可得到适量的相应3-芳基环烷酮，而2-甲基-2-环戊烯-1-醇则可提供单芳基化和双芳基化的混合物环戊酮产品。1-乙酰氧基环戊烯进行芳基化反应，生成相应的烯丙基芳基取代产物，为环烷酮的α-芳基化开辟了一条新途径。环状烯丙基醚在CC双键的两端进行芳基化反应，生成单芳基化乙烯基醚的混合物。1-氰基环戊烯在钯催化下与芳基碘化物反应生成高产率的1-氰基-5-芳基环戊烯。
• METHOD FOR PRODUCING CYCLOPENTYL ALKYL ETHER COMPOUND
  申请人：ZEON CORPORATION

  公开号：US20170217862A1

  公开（公告）日：2017-08-03

  The present invention is a method for producing a cyclopentyl alkyl ether compound comprising reacting substituted or unsubstituted cyclopentene with an alcohol compound represented by a formula (2): R 1 OH in the presence of an acidic zeolite, the cyclopentyl alkyl ether compound being represented by a formula (1): R 1 —O—R 2 , wherein R 1 represents a substituted or unsubstituted alkyl group having 1 to 10 carbon atoms, or a substituted or unsubstituted cycloalkyl group having 3 to 8 carbon atoms, and R 2 represents a substituted or unsubstituted cyclopentyl group. The present invention provides a method that can produce a cyclopentyl alkyl ether with high reaction efficiency through a liquid-phase reaction even when the raw material feed rate (amount) is increased.

  本发明涉及一种制备环戊基烷基醚化合物的方法，包括在酸性沸石的存在下，将取代或未取代的环戊烯与式（2）表示的醇化合物（R1OH）反应，所述环戊基烷基醚化合物由式（1）表示：R1-O-R2，其中R1表示具有1到10个碳原子的取代或未取代的烷基或具有3到8个碳原子的取代或未取代的环烷基，R2表示取代或未取代的环戊基。本发明提供了一种方法，即使原料进料速率（量）增加，也可以通过液相反应高效地生产环戊基烷基醚。
• METHOD FOR PRODUCING CYCLOALKYL ALKYL ETHER COMPOUND
  申请人：ZEON CORPORATION

  公开号：US20160052848A1

  公开（公告）日：2016-02-25

  The present invention is a method for producing a cycloalkyl alkyl ether compound comprising reacting substituted or unsubstituted cyclopentene or substituted or unsubstituted cyclohexene with an alcohol compound represented by a formula (2): R 1 OH (wherein R 1 is a substituted or unsubstituted alkyl group having 1 to 10 carbon atoms, or a substituted or unsubstituted cycloalkyl group having 3 to 8 carbon atoms) in a gaseous state in presence of an acidic ion-exchange resin to produce a cycloalkyl alkyl ether compound represented by a formula (1): R 1 —O—R 2 (wherein R 1 is the same as defined above, and R 2 is a substituted or unsubstituted cyclopentyl group or a substituted or unsubstituted cyclohexyl group), the acidic ion-exchange resin having a specific surface area of 20 to 50 m 2 /g, an average pore size of 20 to 70 nm, and a total exchange capacity of 4.8 to 6.0 eq/L-R wet resin.

  本发明是一种生产环烷基烷基醚化合物的方法，包括将取代或未取代的环戊烯或取代或未取代的环己烯与公式（2）所表示的醇化合物反应：R1OH（其中R1是具有1至10个碳原子的取代或未取代的烷基或具有3至8个碳原子的取代或未取代的环烷基），在酸性离子交换树脂的存在下，在气态下生产环烷基烷基醚化合物，该化合物的化学式为（1）：R1—O—R2（其中R1与上述定义相同，R2是取代或未取代的环戊基或取代或未取代的环己基），酸性离子交换树脂具有20至50 m2/g的比表面积，20至70 nm的平均孔径和4.8至6.0 eq/L-R湿树脂的总交换容量。
• Lewina et al., Vestnik Moskovskogo Universiteta, 1959, vol. 14, # 3, p. 171,173
  作者：Lewina et al.

  DOI：——

  日期：——
• KOPECKY, K. R.;LEVINE, C., CAN. J. CHEM., 1981, 59, N 23, 3273-3279
  作者：KOPECKY, K. R.、LEVINE, C.

  DOI：——

  日期：——