| 23124-67-6

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• CAS: 23124-67-6
• 化学式: C₈H₁₂N₂O₈Pt
• 分子量: 459.272
• InChiKey: VNAWKUQPSSIVAQ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  在 hydrogen peroxide 作用下， 以 水 为溶剂， 以52%的产率得到
  参考文献：
  名称：

  Appleton, Trevor G.; Berry, Ron D.; Hall, John R., Inorganic Chemistry, 1985, vol. 24, # 5, p. 666 - 672

  摘要：

  DOI：
• 作为产物：
  描述：

  potassium tetrachloroplatinate 、 亚氨基二乙酸 以 水 为溶剂， 以76%的产率得到
  参考文献：
  名称：

  Appleton, Trevor G.; Berry, Ron D.; Hall, John R., Inorganic Chemistry, 1985, vol. 24, # 5, p. 666 - 672

  摘要：

  DOI：

文献信息

• Self-assembly of [M(Hida)2] (Hida−=iminodiacetate; M=Pd and Pt) in a 2D supramolecular network via extensive hydrogen bonded interactions: Synthesis, X-ray crystal structure, spectroscopic and thermal studies
  作者：Jishnunil Chakraborty、Heike Mayer-Figge、William S. Sheldrick、Pradyot Banerjee

  DOI：10.1016/j.poly.2004.09.033

  日期：2005.5

  Two hydrogen-bonded palladium(II) and platinum(II) complexes, [Pd(Hida)(2)] (1) and [Pt(Hida)(2)] (2) (Hida(-)= iminodiacetate), have been synthesized and characterized by single crystal X-ray diffraction analyses. Hida(-) serves as a bidentate ligand coordinating to both Pd(II) and Pt(II) through its nitrogen and oxygen atom, exhibiting a square planar geometry with a trans configuration. The uncoordinated carboxylic group and the imino group of the ligand are involved in strong intermolecular hydrogen bonding to form a two dimensional layered network in both the complexes. The network is propagated along the ac-plane and stacks orthogonally to the b-axis. The thermogravimetric analyses for complexes 1 and 2 reveal stepwise decomposition processes indicating the probable decarboxylation of the free and bonded carboxylates. As there are two types of hydrogen bonding (N-(HO)-O-..., O-(HO)-O-...) present in both the complexes, two endothermic peaks regarding heat change are evident from their DSC diagrams. (c) 2005 Elsevier Ltd. All rights reserved.