1-(2,4,6-triisopropylphenyl)-4,6-(diisopropylphenyl)-1-(2-phenyl-3,3-dimethylbut-1-enyl)-3-methylgermacyclopentane | 220927-42-4

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 直链 1,3-二芳基丙烷
• 英文名称: 1-(2,4,6-triisopropylphenyl)-4,6-(diisopropylphenyl)-1-(2-phenyl-3,3-dimethylbut-1-enyl)-3-methylgermacyclopentane
• CAS: 220927-42-4
• 化学式: C₄₂H₆₀Ge
• 分子量: 637.528
• InChiKey: JISKEPZUEFDEJR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.65
• 重原子数：
  43.0
• 可旋转键数：
  8.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.52
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  (2,4,6-triisopropylphenyl)2Ge(F)(CCPh) 以 乙醚 、 正戊烷 为溶剂， 生成 1-(2,4,6-triisopropylphenyl)-4,6-(diisopropylphenyl)-1-(2-phenyl-3,3-dimethylbut-1-enyl)-2,2-dimethylgermacyclobutane 、 1-(2,4,6-triisopropylphenyl)-4,6-(diisopropylphenyl)-1-(2-phenyl-3,3-dimethylbut-1-enyl)-3-methylgermacyclopentane
  参考文献：
  名称：

  Reactivity of a 1-Germapropadiene

  摘要：

  alpha-Lithiofluorogermane 3 eliminated lithium fluoride to give 1-germapropadiene 1 even at -75 degrees C. The reactivity of 1-germapropadiene 1 was investigated. Compound 1 was not stable above 0 degrees C in solution or 90 degrees C in the solid state. Two C-H insertion cyclic compounds, 8 and 9, were formed as a result of decomposition. Water, methanol, and ethanol added across the Ge=C double bond of 1 to give vinylalkoxy (hydroxy) germanes, Benzophenone did not react with 1 at 0 degrees C, but benzaldehyde gave oxagermetane 13 in good yield. When acetone was introduced to 1, it gave the unexpected product 10, the water adduct.

  DOI：

  10.1021/om980555r