cis-1,6-bicyclo<4.3.0>nonanediol | 39837-98-4

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: cis-1,6-bicyclo<4.3.0>nonanediol
• 英文别名: cis-dihydroxynonalin；cis-hexahydro-indene-3a,7a-diol；cis-Hexahydro-inden-3a,7a-diol；cis-1,6-Dihydroxybicyclo<4.3.0>nonan
• CAS: 39837-98-4
• 化学式: C₉H₁₆O₂
• 分子量: 156.225
• InChiKey: BMFPGEPRLDAAEO-DTORHVGOSA-N

物化性质

• 熔点：
  67-67.5 °C
• 沸点：
  273.5±8.0 °C(Predicted)
• 密度：
  1.258±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.21
• 重原子数：
  11.0
• 可旋转键数：
  0.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  40.46
• 氢给体数：
  2.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  cis-1,6-bicyclo<4.3.0>nonanediol 在 manganese(IV) oxide 作用下， 以 二氯甲烷 为溶剂， 反应 3.0h， 生成 6-hydroxybicyclo<4.3.0>nonan-2-one
  参考文献：
  名称：

  Kopecky, Karl R.; Lockwood, Peter A.; Gomez, Rodrigo Rico, Canadian Journal of Chemistry, 1981, vol. 59, p. 851 - 858

  摘要：

  DOI：
• 作为产物：
  描述：

  4,5,6,7-tetrahydroindane 在 四氧化锇 、 乙醚 作用下， 生成 cis-1,6-bicyclo<4.3.0>nonanediol
  参考文献：
  名称：

  Criegee; Zogel, Chemische Berichte, 1951, vol. 84, p. 215,218

  摘要：

  DOI：

文献信息

• Design and synthesis of highly selective ionophores for lithium ion based on 14-crown-4 derivatives for an ion-selective electrode
  作者：Koji. Suzuki、Hiroyuki. Yamada、Kazunari. Sato、Kazuhiko. Watanabe、Hideaki. Hisamoto、Yoshito. Tobe、Kazuya. Kobiro

  DOI：10.1021/ac00071a012

  日期：1993.12.1

  Highly Li+-selective ionophores based on 14-crown-4 derivatives were designed and synthesized, and the relationship of their molecular structures and ion selectivities was investigated in order to obtain a highly Li+-selective electrode. The ion selectivities were examined with 11 kinds of 14-crown-4 derivatives, which were prepared according to the proposed two types of Li+ ionophore models. Excellent Li+-selective ionophores were obtained by introducing a bulky ''block'' subunit into the ethano-bridge section of the base crown ring, which effectively prevents the formation of a 2:1 or 3:1 sandwich-type complex consisting of the crown ether and cations larger than Li+. The best Li+/Na+ selectivity (more than 1000) was obtained for the electrode using the 14-crown-4 derivative with a bulky decalin subunit. These results offer the general ion selectivity features of 14-crown-4-based compounds.