9,9'，9''，9'''-（（（6-苯基-1,3,5-三嗪-2,4-二基）双（苯-5,3,1-三基））四（9H-咔唑） | 1685282-47-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 中文名称: 9,9'，9''，9'''-（（（6-苯基-1,3,5-三嗪-2,4-二基）双（苯-5,3,1-三基））四（9H-咔唑）
• 英文名称: 9,9′,9″,9′′′-((6-phenyl-1,3,5-triazine-2,4-diyl)bis(benzene-5,3,1-triyl))tetrakis(9H-carbazole)
• 英文别名: 9,9',9'',9'''-((6-phenyl-1,3,5-triazine-2,4-diyl)bis(benzene-5,3,1-triyl))tetrakis(9H-carbazole)；DDCzTrz；9-[3-carbazol-9-yl-5-[4-[3,5-di(carbazol-9-yl)phenyl]-6-phenyl-1,3,5-triazin-2-yl]phenyl]carbazole
• CAS: 1685282-47-6
• 化学式: C₆₉H₄₃N₇
• 分子量: 970.147
• InChiKey: XNQXMXOBMDPMNT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  17.3
• 重原子数：
  76
• 可旋转键数：
  7
• 环数：
  16.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  58.4
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  2,4-二氯-6-苯基-1,3,5-三嗪 、 9,9'-(5-频那醇酯-1,3-亚苯基)双(9H-咔唑) 在 四(三苯基膦)钯 、 potassium carbonate 作用下， 以 四氢呋喃 为溶剂， 以85%的产率得到9,9'，9''，9'''-（（（6-苯基-1,3,5-三嗪-2,4-二基）双（苯-5,3,1-三基））四（9H-咔唑）
  参考文献：
  名称：

  稳定的蓝色热激活延迟荧光有机发光二极管，其寿命是磷光有机发光二极管的三倍

  摘要：

  在蓝色热激活延迟荧光OLED中证明了高于18％的高量子效率和比磷光有机发光二极管（OLED）更长的寿命三倍的寿命。

  DOI：

  10.1002/adma.201500267

文献信息

• HETEROCYCLIC COMPOUND AND ORGANIC ELECTROLUMINESCENCE DEVICE INCLUDING THE SAME
  申请人：Samsung Display Co., Ltd.

  公开号：US20190019965A1

  公开（公告）日：2019-01-17

  A heterocyclic compound represented by the following Formula 1 and an organic electroluminescence device including the same are provided. In Formula 1, X 1 and X 2 are each independently represented by any one of the following Formulae 2 to 4:

  提供了一种由下式1表示的杂环化合物，以及包括该化合物的有机电致发光器件。 在式1中，X1和X2分别独立地以下列式2至4的任一式表示：
• ORGANIC MIXTURE AND APPLICATION THEREOF IN ORGANIC ELECTRONIC DEVICES
  申请人：GUANGZHOU CHINARAY OPTOELECTRONIC MATERIALS LTD.

  公开号：US20200317646A1

  公开（公告）日：2020-10-08

  The present invention relates to an organic mixture and an application thereof in organic electronic devices. The organic mixture comprises a spirofluorene organic compound containing a fused heterocyclic ring and an aromatic fused heterocyclic organic compound containing an electron-donating group. A combination of the two materials may be used as a host material of a phosphorescent organic light-emitting diode (OLED), which may use the energy of excitons and balance the charge transport to the greatest extent and which may effectively reduce the concentration of excitons and the operating voltage of a corresponding device, thereby effectively improving the efficiency and service life of the related electronic device in order to provide an effective solution for improving the overall performance of an organic electronic device.

  本发明涉及一种有机混合物及其在有机电子器件中的应用。该有机混合物包括含有螺环异芳烃环的螺芴有机化合物和含有供电子给体基团的芳香融合杂环有机化合物。这两种材料的组合可用作磷光有机发光二极管（OLED）的主体材料，该二极管可以利用激子的能量并最大程度地平衡电荷传输，从而有效降低激子的浓度和相应器件的工作电压，从而有效提高相关电子器件的效率和使用寿命，为改善有机电子器件的整体性能提供有效解决方案。
• COMPOUND INCLUDING NITROGEN AND ORGANIC ELECTROLUMINESCENCE DEVICE INCLUDING THE SAME
  申请人：Samsung Display Co., Ltd.

  公开号：US20190131536A1

  公开（公告）日：2019-05-02

  A compound including nitrogen, represented by Formula 1, and an organic electroluminescence device including the same are provided: In Formula 1, X 1 to X 3 may each independently be CR or N, at least two of X 1 to X 3 may be N, Y 1 to Y 3 may each independently be represented by one of Formulae 2 to 4, and at least two of Y 1 to Y 3 may be represented by Formula 3 or 4: SCC 103531605.4 -*-Apr. 26, 2018 10:14 AM AGJ 103531605.5 -*-Apr. 26, 2018 10:14 AM

  提供一种包含氮的化合物，其化学式为Formula 1，并提供包含该化合物的有机电致发光器件：在Formula 1中，X1到X3可以各自独立地是CR或N，至少两个X1到X3可以是N，Y1到Y3可以各自独立地由Formulae 2至4中的一个表示，至少两个Y1到Y3可以由Formula 3或4表示：SCC103531605.4-*-Apr.26, 2018 10:14AMAGJ103531605.5-*-Apr.26, 2018 10:14AM
• DIBENZO[B,E][1,4]OXASILINE COMPOUNDS AND ORGANIC ELECTROLUMINESCENCE DEVICES INCLUDING THE SAME
  申请人：Samsung Display Co., Ltd.

  公开号：EP3428173A1

  公开（公告）日：2019-01-16

  A heterocyclic compound represented by the following Formula 1 and an organic electroluminescence device including the same are provided. In Formula 1, X1 and X2 are each independently represented by any one of the following Formulae 2 to 4:

  提供了由下式 1 表示的杂环化合物和包括该杂环化合物的有机电致发光器件。 在式 1 中，X1 和 X2 各自独立地由下式 2 至 4 中的任一个表示：
• ORGANIC COMPOUND HAVING IMPROVED LUMINESCENT PROPERTIES, ORGANIC LIGHT EMITTING DIODE AND ORGANIC LIGHT EMITTING DEVICE INCLUDING THE ORGANIC COMPOUND
  申请人：LG Display Co., Ltd.

  公开号：EP3790069A1

  公开（公告）日：2021-03-10

  The present invention relates to an organic compound having improved luminescent properties, an organic light emitting diode and organic light emitting device including the organic compound, the organic compound having a specific structure. The organic compound is a bipolar compound having both a p-type moiety and an n-type moiety. Moreover, the organic compound has high energy levels, large energy bandgap and improved thermal stability. Incorporating the organic compound into an emissive layer of the OLED allows holes and electrons to be recombined at whole area of an emitting material layer, and thereby allows enhancing the luminous efficiency and the luminous lifetime of the OLED.

  本发明涉及一种具有改进发光特性的有机化合物、一种有机发光二极管和包括该有机化合物的有机发光器件，该有机化合物具有特定的结构。该有机化合物是一种双极性化合物，同时具有 p 型分子和 n 型分子。此外，该有机化合物具有高能级、大能带隙和更好的热稳定性。在有机发光二极管的发光层中加入有机化合物，可使空穴和电子在发光材料层的整个区域重新结合，从而提高有机发光二极管的发光效率和发光寿命。