tris[2-(1-vinylimidazolyl)]phosphine | 866016-99-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: tris[2-(1-vinylimidazolyl)]phosphine
• 英文别名: Tris(1-ethenylimidazol-2-yl)phosphine；tris(1-ethenylimidazol-2-yl)phosphane
• CAS: 866016-99-1
• 化学式: C₁₅H₁₅N₆P
• 分子量: 310.298
• InChiKey: MGJMHMMSIYGZEO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.7
• 重原子数：
  22
• 可旋转键数：
  6
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  53.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  copper(II) perchlorate hexahydrate 、 tris[2-(1-vinylimidazolyl)]phosphine 以 甲醇 为溶剂， 以84%的产率得到[Cu(tris[2-(1-vinylimidazolyl)]phosphine)2](ClO4)2*1.5H2O
  参考文献：
  名称：

  Highly Cross-linked Polymers Containing N,N‘,N‘ ‘-Chelate Ligands for the Cu(II)-Mediated Hydrolysis of Phosphoesters

  摘要：

  Three immobilized Cu(II) complexes were generated by the following: (a) homopolymerization of the N,N',N '' chelate ligand tris[2-(1-vinylimidazolyl)]phosphine (1) and subsequent metalation with CuCl2; (b) copolymerization of 1 with ethyleneglycol dimethacrylate (EGDMA) und subsequent metalation with CuCl2; or (c) molecular imprinting with the organometallic Mo-complex (Mo(eta(3)-C4H7)(CO)(2)(1)](TsO) (5) and EGDMA and subsequent replacement of Mo(II) by Cu(II). All three polymeric Cu complexes were found to efficiently promote the hydrolysis of activated phosphoesters with the relative activity being dependent on the nature of the polymer and the substrate.

  DOI：

  10.1021/ic0504588