1,4-diazabicyclo[2,2,2]octane phosphate | 256637-31-7

• 分子结构分类: 有机化合物 - 有机酸及其衍生物
• 英文名称: 1,4-diazabicyclo[2,2,2]octane phosphate
• CAS: 256637-31-7
• 化学式: C₆H₁₂N₂*H₂O*H₃O₄P
• 分子量: 228.185
• InChiKey: BCLZLGILBYDRDA-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  zinc(II) oxide 、 1,4-diazabicyclo[2,2,2]octane phosphate 在 HCl 作用下， 以 水 为溶剂， 生成
  参考文献：
  名称：

  磷酸胺作为开放框架结构形成的中间体。

  摘要：

  链状，阶梯状，层状和三维金属磷酸盐是通过胺磷酸盐与金属离子在温和的水热条件下反应制得的。原位NMR光谱和X射线衍射研究证实了磷酸胺在水热合成中作为中间体的作用。该图显示了在磷酸哌嗪与Zn（II）离子的反应中形成的简单的角共享线性链结构。

  DOI：

  10.1002/(sici)1521-3773(19991203)38:23<3480::aid-anie3480>3.0.co;2-s

文献信息

• Building Open-Framework Metal Phosphates from Amine Phosphates and a Monomeric Four-Membered Ring Phosphate
  作者：C.N.R. Rao、Srinivasan Natarajan、S. Neeraj

  DOI：10.1006/jssc.2000.8676

  日期：2000.6

  chlorophosphate incorporating chlorine as part of the framework, and a four-membered ring monomeric phosphate. The studies indicate that amine phosphates are likely to act as intermediates in the formation of open-framework metal phosphates. The transformation of the monomeric zinc phosphate to an open-framework layered structure on heating it in water suggests the four-membered ring to be the basic building

  已经合成了几种磷酸胺，并通过单晶X射线衍射阐明了它们的结构。磷酸胺与金属离子反应后，会形成多种结合有胺分子的磷酸金属结构，从而提供了通往开放骨架材料的简便途径。通过这种软化学方法，可以产生新颖的结构，典型的是三叶草结构，新的将氯作为框架一部分的氯磷酸盐和四元环单体磷酸盐。研究表明，胺磷酸盐很可能在开放骨架金属磷酸盐的形成中充当中间体。
• Zn3(C6H14N2)3[B6P12O39(OH)12] · (C6H14N2)[HPO4]: A Chiral Borophosphate - Triethylenediammonium Hydrogenphosphate Composite
  作者：Gerd Schäfer、Wilder Carrillo-Cabrera、Stefano Leoni、Horst Borrmann、Rüdiger Kniep

  DOI：10.1002/1521-3749(200201)628:1<67::aid-zaac67>3.0.co;2-n

  日期：2002.1

  A novel borophosphate, Zn-3(C6H14N2)(3)-[B6P12O39(OH)(12)].(C6H14N2)[HPO4] has been synthesised under mild hydrothermal conditions at T = 165degreesC. The chiral crystal structure was determined by single crystal X-ray diffraction data (trigonal, R3 (no. 146), Z = 3, a = 2089.55(4) pm, c = 1237.03(4) pm, V = 4677.5(2) . 10(6) pm(3). R-1 = 0.066, wR(2) = 0.164 for 5100 observed reflections). The title compound can be considered as an ordered composite of the two different and neutral structures which fit into each other: An open framework of composition Zn-3(C6H14N2)(3)[B6P12O39(OH)(12)] and columns of composition (C6H14N2)[HPO4]. The framework structure is formed by mixed octahedral-tetrahedral secondary building units, in a three-dimensional arrangement reflecting a hierarchical derivative of the NbO structure type. The underlying NbO topology is illustrated with the help of Periodic Nodal Surfaces. The composite nature of the compound is resolved in the spatial segregation of two frameworks with a separating surface.