tris[2-(morpholin-4-ylmethyl)phenyl-κ(2)C(1),N]antimony(III) | 1131341-19-9

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: tris[2-(morpholin-4-ylmethyl)phenyl-κ(2)C(1),N]antimony(III)
• 英文别名: antimony(3+);4-(phenylmethyl)morpholine
• CAS: 1131341-19-9
• 化学式: C₃₃H₄₂N₃O₃Sb
• 分子量: 650.465
• InChiKey: KTGUQMGGNWNKIU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.58
• 重原子数：
  40
• 可旋转键数：
  6
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  37.4
• 氢给体数：
  0
• 氢受体数：
  9

反应信息

• 作为产物：
  描述：

  三氯化锑 、 2-[O(C2CH2)2NCH2]C6H4Li 以 乙醚 为溶剂， 以68%的产率得到tris[2-(morpholin-4-ylmethyl)phenyl-κ(2)C(1),N]antimony(III)
  参考文献：
  名称：

  Tris[2-(morpholin-4-ylmethyl)phenyl-κ²C¹,N]antimony(III)

  摘要：

  The title compound, [Sb(C11H14NO) 3], is monomeric with the Sb atom located on a threefold axis. The complex exhibits distorted trigonal-antiprismatic geometry around the Sb atom, owing to the presence of intramolecular N -> Sb interactions. H center dot center dot center dot phenyl intermolecular interactions lead to the formation of dimers stacked along the c axis. The morpholine rings exhibit almost ideal chair conformations. No intermolecular interactions between the morpholine rings of neighbouring molecules were observed.

  DOI：

  10.1107/s0108270107061896