bis(2-[(diethylamino)methyl]phenolato)copper(II) | 189257-03-2

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: bis(2-[(diethylamino)methyl]phenolato)copper(II)
• 英文别名: bis(2-diethylaminomethylphenolate)copper(II)；copper;2-(diethylaminomethyl)phenolate
• CAS: 189257-03-2；82809-73-2
• 化学式: C₂₂H₃₂CuN₂O₂
• 分子量: 420.054
• InChiKey: LKROESLLYIYDMM-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  copper(II) choride dihydrate 、 o-dimethylaminomethylphenol 在 Et₃N 作用下， 以 甲醇 为溶剂， 生成 bis(2-[(diethylamino)methyl]phenolato)copper(II)
  参考文献：
  名称：

  Zinc(II) and copper(II) complexes of monoanionic chelating phenolato ligands containing an amine donor. Crystal and molecular structure of the (Et3NH)[ZnCl2L] and CuL2 compounds with L=2-[(diethylamino)methyl]-4-methylphenolate

  摘要：

  The reaction of ZnCl2 with 2-[(diethylamino)methyl]phenol (AH) or 2-[(diethylamino)methyl]-4-methylphenol (BH) in the presence of NEt3 (1:1:1 ratio) gave good yields of the complexes (Et3NH) [ZnCl2L] (L = A (1), B (2)); Colourless crystals of 2 (monoclinic, P2(1)/c, a = 13.767, b = 11.650, c = 14.789 Angstrom, beta = 109.66 degrees, Z = 4, R = 0.042) contain monomeric tetrahedral zincate anions in which the metal is surrounded by two Cl atoms and one bidentate aminophenolato ligand. The Et3NH+ counter cation is hydrogen-bonded to the coordinated phenolate oxygen, Brown CuL2 complexes (L = A (3), B (4)) were obtained by reacting Cu(NO3)(2) . 3H(2)O, CuCl2 . 2H(2)O or CuSO4 . 3H(2)O with AH and BH, respectively, in the presence of NEt3 in a 1:2:2 Cu:ligand:NEt3 ratio, Crystals of 4 (monoclinic, P2(1)/c, a = 8.165, b = 14.798, c = 9.481 Angstrom, beta = 90.91 degrees, Z = 2, R = 0.048) contain monomeric square-planar copper centres surrounded by two bidentate aminophenolato ligands in a trans arrangement. The presence of relatively bulky ethyl substituents on the amino group favours the monomeric chelates by preventing the formation of phenolate-bridged polynuclear arrangements.

  DOI：

  10.1016/s0020-1693(96)05425-4

文献信息

• Ryzhkina, I. S.; Boos, G. A.; Kudryavtseva, L. A., Russian Journal of Inorganic Chemistry, 1983, vol. 28, p. 1151 - 1153
  作者：Ryzhkina, I. S.、Boos, G. A.、Kudryavtseva, L. A.、Bel'skii, V. E.、Ivanov, B. E.

  DOI：——

  日期：——
• Complex formation of copper(II) with 2-diethylaminomethylphenol in ethanol-water solutions
  作者：I. S. Ryzhkina、L. A. Kudryaztseva、G. A. Boos、V. E. Bel'skii、B. E. Ivanov

  DOI：10.1007/bf00962490

  日期：1988.9
• KUDRYAVTSEVA, L. A.;MOLODYX, ZH. V.;PANTELEEVA, A. R.;RYZHKINA, I. S.;MIR+, XIMIYA I TEXNOL. EHLEMENTOORGAN. SOED. I POLIMEROV , KAZAN,(1989) S. 3-11
  作者：KUDRYAVTSEVA, L. A.、MOLODYX, ZH. V.、PANTELEEVA, A. R.、RYZHKINA, I. S.、MIR+

  DOI：——

  日期：——