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[(2R,4R,6R,8R)-2',4',6',8'-tetramethyldecyl]-β-D-galactopyranoside | 691869-84-8

中文名称
——
中文别名
——
英文名称
[(2R,4R,6R,8R)-2',4',6',8'-tetramethyldecyl]-β-D-galactopyranoside
英文别名
——
[(2R,4R,6R,8R)-2',4',6',8'-tetramethyldecyl]-β-D-galactopyranoside化学式
CAS
691869-84-8
化学式
C20H40O6
mdl
——
分子量
376.534
InChiKey
VOUTXLAIMBWIQA-HIGSRJIRSA-N
BEILSTEIN
——
EINECS
——
  • 物化性质
  • 计算性质
  • ADMET
  • 安全信息
  • SDS
  • 制备方法与用途
  • 上下游信息
  • 反应信息
  • 文献信息
  • 表征谱图
  • 同类化合物
  • 相关功能分类
  • 相关结构分类

计算性质

  • 辛醇/水分配系数(LogP):
    1.93
  • 重原子数:
    26.0
  • 可旋转键数:
    11.0
  • 环数:
    1.0
  • sp3杂化的碳原子比例:
    1.0
  • 拓扑面积:
    99.38
  • 氢给体数:
    4.0
  • 氢受体数:
    6.0

反应信息

  • 作为反应物:
    描述:
    [(2R,4R,6R,8R)-2',4',6',8'-tetramethyldecyl]-β-D-galactopyranosidesodium hypochlorite 2,2,6,6-tetramethyl-piperidine-N-oxyl 、 碳酸氢钠 、 potassium bromide 作用下, 以38%的产率得到[(2R,4R,6R,8R)-2',4',6',8'-tetramethyldecyl]-β-D-galactopyranoside uronic acid
    参考文献:
    名称:
    Thermotropic and lyotropic properties of long chain alkyl glycopyranosides
    摘要:
    As part of a series of papers, the influence of carbohydrate headgroups and aliphatic chains on the mesogenic properties of glycolipids was investigated. Alkyl glycosides with different types of aliphatic chains were synthesised. Neutral glycolipids were oxidized to their uronic acid derivatives, using the well established TEMPO-oxidation. For comparison a 6-deoxy-6-amino alkylglucopyranoside was synthesised. In addition, the thermotropic and lyotropic phase behaviour of the synthesised compounds were investigated. The thermotropism was characterised by polarising microscopy, the lyotropism by the contact preparation method. (C) 2003 Elsevier Ireland Ltd. All rights reserved.
    DOI:
    10.1016/j.chemphyslip.2003.09.007
  • 作为产物:
    参考文献:
    名称:
    Thermotropic and lyotropic properties of long chain alkyl glycopyranosides
    摘要:
    As part of a series of papers, the influence of carbohydrate headgroups and aliphatic chains on the mesogenic properties of glycolipids was investigated. Alkyl glycosides with different types of aliphatic chains were synthesised. Neutral glycolipids were oxidized to their uronic acid derivatives, using the well established TEMPO-oxidation. For comparison a 6-deoxy-6-amino alkylglucopyranoside was synthesised. In addition, the thermotropic and lyotropic phase behaviour of the synthesised compounds were investigated. The thermotropism was characterised by polarising microscopy, the lyotropism by the contact preparation method. (C) 2003 Elsevier Ireland Ltd. All rights reserved.
    DOI:
    10.1016/j.chemphyslip.2003.09.007
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