3-hydroxypropyl norbornene-5-carboxylate | 118149-74-9

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 3-hydroxypropyl norbornene-5-carboxylate
• 英文别名: 3-Hydroxypropyl 5-norbomene-2-carboxylate；3-hydroxypropyl bicyclo[2.2.1]hept-5-ene-2-carboxylate
• CAS: 118149-74-9
• 化学式: C₁₁H₁₆O₃
• 分子量: 196.246
• InChiKey: MYBZOQDIRORKOI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.2
• 重原子数：
  14
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.73
• 拓扑面积：
  46.5
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  3-ethyl-1H-pyrrole-2,5-dione 、 t-Butyl bicyclo[2,2,2]oct-5-ene-2-carboxylate 、 3-hydroxypropyl norbornene-5-carboxylate 、 偶氮二异丁腈 在 氮 、 resultant product 、 乙醚 、 正己烷 作用下， 以 四氢呋喃 为溶剂， 反应 10.0h， 以was obtained at a yield of about 83%的产率得到Ethyl maleimide t-butyl bicyclo[2,2,2]oct-5-ene-2-carboxylate 3-hydroxypropyl 5-norbornene-2-carboxylate
  参考文献：
  名称：

  Polymer and a forming method of a micro pattern using the same

  摘要：

  本发明涉及以下式1所表示的聚合物及其制备微型图案的方法：其中R1是C1-C10直链或支链取代烷基或苄基；R2是C1-C10一级、二级或三级醇基；m和n独立地表示1到3的数字；X、Y和Z是共聚单体的聚合比例。本发明的光阻聚合物适用于使用ArF、电子束、EUV或离子束等光源制备4G或16G DRAM半导体器件等超微型图案。

  公开号：

  US06225020B1
• 作为产物：
  描述：

  环戊二烯 、 3-羟丙基丙烯酸酯 、 、 四氢呋喃 反应 10.0h， 生成 3-hydroxypropyl norbornene-5-carboxylate
  参考文献：
  名称：

  Semiconductor device using polymer-containing photoresist, and process for manufacturing the same

  摘要：

  本发明涉及一种使用共聚物含有的光阻的半导体器件及其制造方法。通过合成具有亲水基的萘并衍生物（单体）并将其引入聚合物的骨架链中，本发明的聚合物具有杂环烯烃结构的特点，具有优异的蚀刻抗性和耐热性，并由于引入亲水基（—OH）而显着提高了粘附性，从而提供了优异的分辨率。

  公开号：

  US20010053834A1

文献信息

• Additive for photoresist composition for resist flow process
  申请人：Hynix Semiconductor Inc.

  公开号：US20040166437A1

  公开（公告）日：2004-08-26

  The present invention provides an additive for a photoresist composition for a resist flow process. A compound of following Formula 1 having low glass transition temperature is added to a photoresist composition containing a polymer which is not suitable for the resist flow process due to its high glass transition temperature, thus improving a flow property of the photoresist composition. As a result, the photoresist composition comprising an additive of Formula 1 can be used for the resist flow process. 1 wherein, A, B, R and R′ are as defined in the specification of the invention.

  本发明提供了一种用于光阻流程的光阻组合物添加剂。将具有低玻璃转移温度的以下式1化合物添加到包含由于其高玻璃转移温度而不适用于阻抗流程的聚合物的光阻组合物中，从而改善光阻组合物的流动性能。因此，含有式1添加剂的光阻组合物可用于阻抗流程。其中，A、B、R和R'如本发明规范中所定义。
• Polymers and photoresist compositions using the same
  申请人：Hyundai Electronics Industries Co., Ltd.

  公开号：US06391518B1

  公开（公告）日：2002-05-21

  The present invention provides a photoresist monomer represented by the following formula 2; a photoresist copolymer represented by the following formula 100; and a photoresist composition containing the same. wherein, R1 and R2 are independently —COOH or —R—COOH; and R is a substituted or unsubstituted (C1-C10) alkyl. wherein, R1 and R2 are independently —COOH or —R—COOH ; R is a substituted or unsubstituted (C1-C10) alkyl; R3 is —COOR* or —R′COOR*; R* is an acid labile group; R′ is a substituted or unsubstituted (C1-C10) alkyl; R4 is H or R3; R5 is a substituted or unsubstituted (C1-C10) alkyl; and a:b:c is the polymerization ratio of the comonomer.

  本发明提供了一种由以下化学式2表示的光阻单体；由以下化学式100表示的光阻共聚物；以及包含它们的光阻组合物。其中，R1和R2独立地为—COOH或—R—COOH；R是取代或未取代的（C1-C10）烷基。其中，R1和R2独立地为—COOH或—R—COOH；R是取代或未取代的（C1-C10）烷基；R3为—COOR*或—R′COOR*；R*为酸敏感基团；R′为取代或未取代的（C1-C10）烷基；R4为H或R3；R5为取代或未取代的（C1-C10）烷基；a:b:c为共聚单体的聚合比。
• OPEN-RING COPOLYMER, HYDROGENATED OPEN-RING COPOLYMER, PROCESSES FOR PRODUCTION OF BOTH, AND COMPOSITIONS
  申请人：Zeon Corporation

  公开号：EP1408064A1

  公开（公告）日：2004-04-14

  A ring-opened metathesis copolymer and its hydrogenated product having a desired monomer unit ratio and a high molecular weight and having hydroxyl groups or hydroxycarbonyl groups can be obtained by conducting a ring-opening metathesis copolymerization of a norbornene-type monomer having hydroxyl groups or hydroxycarbonyl groups with an unsubstituted norbornene-type monomer having at least three rings in the presence of a catalyst predominantly comprised of an organic ruthenium compound having coordinated therewith a neutral electron-donating ligand, and, if desired, hydrogenating the resulting copolymer. The thus-obtained ring-opened metathesis copolymer and its hydrogenation product are characterized by having a low water absorption, good adhesion to metal and other materials, good compatibility with a curing agent and other compounds, and high heat resistance, and exhibiting reduced signal retardation and signal noise.

  在主要由有机钌化合物组成的催化剂存在下，将具有羟基或羟羰基的降冰片烯类单体与具有至少三个环的未取代降冰片烯类单体进行开环偏析共聚，可获得具有所需单体单元比和高分子量且具有羟基或羟羰基的开环偏析共聚物及其氢化产物、如果需要，对得到的共聚物进行氢化。这样得到的开环偏聚共聚物及其氢化产物的特点是吸水性低，与金属和其他材料的粘附性好，与固化剂和其他化合物的相容性好，耐热性高，并能减少信号延迟和信号噪声。
• Ring-opened copolymer, hydrogenated ring-opened copolymer, process for producing thereof, and compositions
  申请人：ZEON CORPORATION

  公开号：EP1803761A1

  公开（公告）日：2007-07-04

  A ring-opened metathesis copolymer and its hydrogenated product having a desired monomer unit ratio and a high molecular weight and having hydroxyl groups can be obtained by conducting a ring-opening metathesis copolymerization of a norbornene-type monomer having hydroxyl groups with an unsubstituted norbornene-type monomer having at least three rings in the presence of a catalyst predominantly comprised of an organic ruthenium compound having coordinated therewith a neutral electron-donating ligand, and, if desired, hydrogenating the resulting copolymer. The thus-obtained ring-opened metathesis copolymer and its hydrogenation product are characterized by having a low water absorption, good adhesion to metal and other materials, good compatibility with a curing agent and other compounds, and high heat resistance, and exhibiting reduced signal retardation and signal noise.

  在主要由有机钌化合物组成的催化剂存在下，将具有羟基的降冰片烯类单体与具有至少三个环的未取代降冰片烯类单体进行开环偏析共聚，并在需要时对所得共聚物进行氢化，可获得具有所需单体单元比和高分子量且具有羟基的开环偏析共聚物及其氢化产物。这样得到的开环偏聚共聚物及其氢化产物的特点是吸水性低，与金属和其他材料的粘附性好，与固化剂和其他化合物的相容性好，耐热性高，并能减少信号延迟和信号噪声。
• Open-ring copolymer, hydrogenated open-ring copolymer, process for production of both, and compositions
  申请人：——

  公开号：US20040152843A1

  公开（公告）日：2004-08-05

  A ring-opened metathesis copolymer and its hydrogenated product having a desired monomer unit ratio and a high molecular weight and having hydroxyl groups or hydroxycarbonyl groups can be obtained by conducting a ring-opening metathesis copolymerization of a norbornene-type monomer having hydroxyl groups or hydroxycarbonyl groups with an unsubstituted norbornene-type monomer having at least three rings in the presence of a catalyst predominantly comprised of an organic ruthenium compound having coordinated therewith a neutral electron-donating ligand, and, if desired, hydrogenating the resulting copolymer. The thus-obtained ring-opened metathesis copolymer and its hydrogenation product are characterized by having a low water absorption, good adhesion to metal and other materials, good compatibility with a curing agent and other compounds, and high heat resistance, and exhibiting reduced signal retardation and signal noise.

  在主要由有机钌化合物组成的催化剂存在下，将具有羟基或羟羰基的降冰片烯类单体与具有至少三个环的未取代降冰片烯类单体进行开环偏析共聚，可获得具有所需单体单元比和高分子量且具有羟基或羟羰基的开环偏析共聚物及其氢化产物、如果需要，对得到的共聚物进行氢化。这样得到的开环偏聚共聚物及其氢化产物的特点是吸水性低，与金属和其他材料的粘附性好，与固化剂和其他化合物的相容性好，耐热性高，并能减少信号延迟和信号噪声。