2,2'-(oxalyldiimino)bis(acetophenone) | 35418-47-4

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 2,2'-(oxalyldiimino)bis(acetophenone)
• 英文别名: 2,2'-(oxalyldiimino)bisacetophenone；oxalic acid bis-(2-acetyl-anilide)；Oxalsaeure-bis-(2-acetyl-anilid)；N,N'-Bis-<2-acetyl-phenyl>-oxamid；Oxamide, N,N'-bis(2'-acetylphenyl)-；N,N'-bis(2-acetylphenyl)oxamide
• CAS: 35418-47-4
• 化学式: C₁₈H₁₆N₂O₄
• 分子量: 324.336
• InChiKey: AFZZGVYHTHBQBS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  24
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  92.3
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  2,2'-(oxalyldiimino)bis(acetophenone) 以 乙醇 为溶剂， 生成 [cobalt(III)(2,3-dioxo-5,6;13,14-dibenzo-7,12-dimethyl-1,4,8,11-tetraazacyclotetradeca-7,11-diene-2H)(N3)2)2Cd(ethanol)2]*2H2O
  参考文献：
  名称：

  Synthesis and crystal structures of the first cobalt complexes of macrocyclic oxamido

  摘要：

  One novel macrocyclic oxamido-cobalt (II) complex CoL (H2L = 2,3-dioxo-5,6; 13,14-dibenzo-7,12-dimethyl-1,4,8,11-tetraazacyclotetradeca-7,11-diene) (1) has been synthesized solvothermally and characterized by X-ray diffraction analysis. By using the mononuclear cobalt complex as a building block and N-3 as auxiliary groups, a trinuclear complex (CoL)(2)Mn(N-3)(4)center dot 2H2O (2) and two one-dimensional complexes (CoL)(2)Cd(N-3)(4)center dot 2H2O (3), (CoL)(2)Co(N-3)(4)center dot 2H2O (4) have been prepared by stepwise synthesis and characterized. The structure of complex 1 consists of a neutral cobalt (II) complex of the [14] N-4 macrocyclic oxamido dianion. In complex 2, the center manganese (II) ion is in a slightly distorted octahedral environment and N-3 groups only act as terminal ligands. Complex 3 and 4 are similar in structure and both show a one-dimensional chain structure via oxamido and N-3 ligands. N-3 ligands show two kinds of coordination mode. In complex 2-4, cobalt ion in the ring is trivalence. (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2012.04.022
• 作为产物：
  描述：

  草酰氯 、 邻氨基苯乙酮 生成 2,2'-(oxalyldiimino)bis(acetophenone)
  参考文献：
  名称：

  Schofield, Journal of the Chemical Society, 1954, p. 4034

  摘要：

  DOI：

文献信息

• Tetraketopiperazine unit-containing compound as an active material in batteries
  申请人：IM&T Research, Inc.

  公开号：US20030148188A1

  公开（公告）日：2003-08-07

  Compounds containing at least one tetraketopiperazine-1,4-diyl unit are disclosed as active materials in the positive electrodes of batteries. Novel methods for preparing the tetraketopiperazine unit-containing compounds include: (i) reacting an oxalyl halide and an oxamide, and adding water or an aqueous alkali solution to the reaction mixture, (ii) reacting an oxalyl halide and a silylamine, (iii) reacting an oximidyl halide and an amine, (iv) reacting an oxalyl halide and a silylamine, and reacting with an amine, (v) reacting an oxalyl halide and a dioxamide, (vi) reacting an oximidyl halide and a diamine, and (vii) reacting an oxalyl halide and a silylamine, and reacting with a diamine. A novel method for preparing an oximidyl halide is also disclosed.

  已公开的含至少一个四酮哌嗪-1,4-二基单元的化合物可作为电池正极的活性材料。制备含四酮哌嗪单元化合物的新方法包括(i) 使草酰基卤化物和草酰胺反应，并向反应混合物中加入水或碱水溶液；(ii) 使草酰基卤化物和硅胺反应；(iii) 使草酰亚胺基卤化物和胺反应、(iv) 草酰卤和硅胺反应，并与胺反应， (v) 草酰卤和二噁酰胺反应， (vi) 草酰亚胺卤和二胺反应， (vii) 草酰卤和硅胺反应，并与二胺反应。此外，还公开了一种制备草酰亚胺卤化物的新方法。
• Christodoulou; Kanatzidis; Coucouvanis, Inorganic Chemistry, 1990, vol. 29, # 2, p. 191 - 201
  作者：Christodoulou、Kanatzidis、Coucouvanis

  DOI：——

  日期：——
• Black, David St. C.; Vanderzalm, Corrie H. Bos; Wong, Laurence C. H., Australian Journal of Chemistry, 1982, vol. 35, p. 2435 - 2444
  作者：Black, David St. C.、Vanderzalm, Corrie H. Bos、Wong, Laurence C. H.

  DOI：——

  日期：——
• US6737193B2
  申请人：——

  公开号：US6737193B2

  公开（公告）日：2004-05-18
• Schofield, Journal of the Chemical Society, 1954, p. 4034
  作者：Schofield

  DOI：——

  日期：——