2-(1,3-dimethyl-2-cyclohexenyl)ethanealdehyde | 38857-65-7

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 2-(1,3-dimethyl-2-cyclohexenyl)ethanealdehyde
• 英文别名: 2-(1,3-dimethyl-2-cyclohexenyl)ethanaldehyde；2-(1,3-dimethyl-2-cyclohexenyl)ethanal；2-(1,3-Dimethylcyclohex-2-en-1-yl)acetaldehyde
• CAS: 38857-65-7
• 化学式: C₁₀H₁₆O
• 分子量: 152.236
• InChiKey: ZPFFPJDCWJPHGL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  11
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.7
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

文献信息

• 7-METHYL-3-METHYLENE-7-OCTENAL ACETAL COMPOUND AND METHODS FOR PRODUCING ALDEHYDE COMPOUND AND ESTER COMPOUND USING THE SAME
  申请人：Shin-Etsu Chemical Co., Ltd.

  公开号：US20180155267A1

  公开（公告）日：2018-06-07

  There are provided methods of efficiently producing compounds that are, for example, sex pheromones of San Jose Scale. For example, there is provided a method for producing a 7-methyl-3-methylene-7-octenyl carboxylate compound (4), the method including the steps of: hydrolyzing a 7-methyl-3-methylene-7-octenal acetal compound (1) to obtain 7-methyl-3-methylene-7-octenal (2); reducing the 7-methyl-3-methylene-7-octenal (2) to obtain 7-methyl-3-methylene-7-octenol (3); and esterifying the 7-methyl-3-methylene-7-octenol (3) to obtain a 7-methyl-3-methylene-7-octenyl carboxylate compound (4).

  提供了一种有效生产化合物的方法，例如圣何塞蚜虫的性信息素。例如，提供了一种生产7-甲基-3-亚甲基-7-辛烯基羧酸酯化合物（4）的方法，该方法包括以下步骤：水解7-甲基-3-亚甲基-7-辛烯醛缩合物（1）以获得7-甲基-3-亚甲基-7-辛烯醛（2）；还原7-甲基-3-亚甲基-7-辛烯醛（2）以获得7-甲基-3-亚甲基-7-辛烯醇（3）；酯化7-甲基-3-亚甲基-7-辛烯醇（3）以获得7-甲基-3-亚甲基-7-辛烯基羧酸酯化合物（4）。
• 7-methyl-3-methylene-7-octenal acetal compound and methods for producing aldehyde compound and ester compound using the same
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：US10611718B2

  公开（公告）日：2020-04-07

  There are provided methods of efficiently producing compounds that are, for example, sex pheromones of San Jose Scale. For example, there is provided a method for producing a 7-methyl-3-methylene-7-octenyl carboxylate compound (4), the method including the steps of: hydrolyzing a 7-methyl-3-methylene-7-octenal acetal compound (1) to obtain 7-methyl-3-methylene-7-octenal (2); reducing the 7-methyl-3-methylene-7-octenal (2) to obtain 7-methyl-3-methylene-7-octenol (3); and esterifying the 7-methyl-3-methylene-7-octenol (3) to obtain a 7-methyl-3-methylene-7-octenyl carboxylate compound (4).

  本发明提供了高效生产圣何塞鳞片性信息素等化合物的方法。例如，提供了一种生产 7-甲基-3-亚甲基-7-辛烯羧酸酯化合物（4）的方法，该方法包括以下步骤：水解 7-甲基-3-亚甲基-7-辛烯醛缩醛化合物 (1)，得到 7-甲基-3-亚甲基-7-辛烯醛 (2)；还原 7-甲基-3-亚甲基-7-辛烯醛 (2)，得到 7-甲基-3-亚甲基-7-辛烯醇 (3)；以及酯化 7-甲基-3-亚甲基-7-辛烯醇 (3)，得到 7-甲基-3-亚甲基-7-辛烯羧酸酯化合物 (4)。
• 7-METHYL-3-METHYLENE-7-OCTENAL ACETAL COMPUND AND METHODS FOR PRODUCING ALDEHYDE COMPOUND AND ESTER COMPOUND USING THE SAME
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：US20200181059A1

  公开（公告）日：2020-06-11

  There are provided methods of efficiently producing compounds that are, for example, sex pheromones of San Jose Scale. For example, there is provided a method for producing a 7-methyl-3-methylene-7-octenyl carboxylate compound (4), the method including the steps of: hydrolyzing a 7-methyl-3-methylene-7-octenal acetal compound (1) to obtain 7-methyl-3-methylene-7-octenal (2); reducing the 7-methyl-3-methylene-7-octenal (2) to obtain 7-methyl-3-methylene-7-octenol (3); and esterifying the 7-methyl-3-methylene-7-octenol (3) to obtain a 7-methyl-3-methylene-7-octenyl carboxylate compound (4).