tetradodecyl-benzophenone hydrazone | 910316-72-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: tetradodecyl-benzophenone hydrazone
• 英文别名: Bis(3,4-didodecoxyphenyl)methylidenehydrazine
• CAS: 910316-72-2
• 化学式: C₆₁H₁₀₈N₂O₄
• 分子量: 933.54
• InChiKey: CXPCKHMZZPEDSS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  25.4
• 重原子数：
  67
• 可旋转键数：
  50
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.79
• 拓扑面积：
  75.3
• 氢给体数：
  1
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  tetradodecyl-benzophenone hydrazone 在 nickel(IV) oxide 、 sodium hydroxide 、 potassium permanganate 、 magnesium sulfate 、 三苯基膦 作用下， 以 乙醇 、 二氯甲烷 、 对二甲苯 、 丙酮 为溶剂， 反应 15.5h， 生成 13-[Bis-(3,4-bis-dodecyloxy-phenyl)-methylene]-13H-pentacen-6-one
  参考文献：
  名称：

  Transferring Self-Assembled, Nanoscale Cables into Electrical Devices

  摘要：

  This study details a new derivative of the contorted HBCs that self-organizes into one-dimensional, single-crystalline fibers. X-ray diffraction, transmission electron microscopy, and electron diffraction studies show that they have an orthorhombic unit cell with dimensions of 5.8 nm x 4.5 nm x 0.45 nm. Each fiber is composed of a few thousands columns. A method is put forth that utilizes elastomer stamps to manipulate and position isolated fibers in organic field effect transistors.

  DOI：

  10.1021/ja0642360
• 作为产物：
  描述：

  1,2-(二十二烷氧荃)苯 在 氯化亚砜 、 一水合肼 作用下， 以 戊醇 为溶剂， 反应 26.0h， 生成 tetradodecyl-benzophenone hydrazone
  参考文献：
  名称：

  Transferring Self-Assembled, Nanoscale Cables into Electrical Devices

  摘要：

  This study details a new derivative of the contorted HBCs that self-organizes into one-dimensional, single-crystalline fibers. X-ray diffraction, transmission electron microscopy, and electron diffraction studies show that they have an orthorhombic unit cell with dimensions of 5.8 nm x 4.5 nm x 0.45 nm. Each fiber is composed of a few thousands columns. A method is put forth that utilizes elastomer stamps to manipulate and position isolated fibers in organic field effect transistors.

  DOI：

  10.1021/ja0642360

文献信息

• Expeditious Synthesis of Contorted Hexabenzocoronenes
  作者：Kyle N. Plunkett、Kamil Godula、Colin Nuckolls、Noah Tremblay、Adam C. Whalley、Shengxiong Xiao

  DOI：10.1021/ol9001834

  日期：2009.6.4

  Contorted hexabenzocoronenes (HBCs) have been synthesized in an expedited manner utilizing a double Barton-Kellogg olefination reaction and a subsequent Scholl cyclization. The scope of both transformations was investigated using a series of pentacene quinones and double olefin precursors. The utility,of these reactions to help create functionalized and oligomeric HBCs in a rapid manner is demonstrated.
• Transferring Self-Assembled, Nanoscale Cables into Electrical Devices
  作者：Shengxiong Xiao、Jinyao Tang、Tobias Beetz、Xuefeng Guo、Noah Tremblay、Theo Siegrist、Yimei Zhu、Michael Steigerwald、Colin Nuckolls

  DOI：10.1021/ja0642360

  日期：2006.8.1

  This study details a new derivative of the contorted HBCs that self-organizes into one-dimensional, single-crystalline fibers. X-ray diffraction, transmission electron microscopy, and electron diffraction studies show that they have an orthorhombic unit cell with dimensions of 5.8 nm x 4.5 nm x 0.45 nm. Each fiber is composed of a few thousands columns. A method is put forth that utilizes elastomer stamps to manipulate and position isolated fibers in organic field effect transistors.