| 1072119-24-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• CAS: 1072119-24-4
• 化学式: C₁₄₆H₂₄₀N₄O₉Zn
• 分子量: 2260.92
• InChiKey: WHTTUFNOMQBWQR-NLPDVBIFSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  在 2,3-二氯-5,6-二氰基-1,4-苯醌 、 scandium tris(trifluoromethanesulfonate) 作用下， 以 甲苯 为溶剂， 反应 12.0h， 以37%的产率得到
  参考文献：
  名称：

  Prominent Electron Transport Property Observed for Triply Fused Metalloporphyrin Dimer: Directed Columnar Liquid Crystalline Assembly by Amphiphilic Molecular Design

  摘要：

  A triply fused copper porphyrin dimer, when site-specifically modified on its periphery with hydrophobic and hydrophilic wedges (1(C12/TEG)), self-assembles into a columnar liquid crystalline (LC) mesophase over a wide-temperature range from -17 to 99 degrees C but gives rise to an amorphous solid when modified with only hydrophobic (1(C12/C12)) or hydrophilic wedges (1(TEG/TED)). ALC film, of 1(C12/TEG) displays at 16 degrees C a top-class one-dimensional electron mobility (0.27 cm(2)/V.s), as evaluated from its maximum flash-photolysis time-resolved microwave conductivity.

  DOI：

  10.1021/ja8030714
• 作为产物：
  描述：

  、 5-溴-1,2,3-三(十二烷氧基)苯 在 四(三苯基膦)钯 、 caesium carbonate 作用下， 以 N,N-二甲基甲酰胺 、 甲苯 为溶剂， 反应 12.0h， 以1.75 g的产率得到
  参考文献：
  名称：

  Prominent Electron Transport Property Observed for Triply Fused Metalloporphyrin Dimer: Directed Columnar Liquid Crystalline Assembly by Amphiphilic Molecular Design

  摘要：

  A triply fused copper porphyrin dimer, when site-specifically modified on its periphery with hydrophobic and hydrophilic wedges (1(C12/TEG)), self-assembles into a columnar liquid crystalline (LC) mesophase over a wide-temperature range from -17 to 99 degrees C but gives rise to an amorphous solid when modified with only hydrophobic (1(C12/C12)) or hydrophilic wedges (1(TEG/TED)). ALC film, of 1(C12/TEG) displays at 16 degrees C a top-class one-dimensional electron mobility (0.27 cm(2)/V.s), as evaluated from its maximum flash-photolysis time-resolved microwave conductivity.

  DOI：

  10.1021/ja8030714

文献信息

• Electron- or Hole-Transporting Nature Selected by Side-Chain-Directed π-Stacking Geometry: Liquid Crystalline Fused Metalloporphyrin Dimers
  作者：Tsuneaki Sakurai、Kentaro Tashiro、Yoshihito Honsho、Akinori Saeki、Shu Seki、Atsuhiro Osuka、Atsuya Muranaka、Masanobu Uchiyama、Jungeun Kim、Sunyeo Ha、Kenichi Kato、Masaki Takata、Takuzo Aida

  DOI：10.1021/ja201272t

  日期：2011.5.4

  Novel liquid crystalline (LC) semiconductors were prepared from the copper complex of a fused porphyrin dimer as the electroactive core by attaching to its periphery dodecyl and semifluoroalkyl side chains site-specifically (P P-hetero) and semifluoroalkyl side chains alone (P P-homo). The former and latter formed rectangular columnar and orthorhombic LC mesophases, respectively, where the stacking geometries of the pi-conjugated core are quite different from one another. Although the pi-electronic properties of the core units in P P-hetero and P P-homo in solution are substantially identical to one another, transient photocurrent profiles of their LC states under time-of-flight conditions clearly showed that P P-hetero behaves as an n-type semiconductor, whereas P P-homo, in contrast, behaves as a p-type semiconductor.