5-(1-Methoxy-1-methyl-ethyl)-bicyclo[2.2.1]hept-2-ene | 908372-15-6

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 5-(1-Methoxy-1-methyl-ethyl)-bicyclo[2.2.1]hept-2-ene
• 英文别名: 5-(2-Methoxypropan-2-yl)bicyclo[2.2.1]hept-2-ene
• CAS: 908372-15-6
• 化学式: C₁₁H₁₈O
• 分子量: 166.263
• InChiKey: WDCYQFXUMUEUNX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  12
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.82
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

文献信息

• GENERATION OF ENDO- AND/OR EXO-NORBORNENECARBOXALDEHYDE AS AN INTERMEDIATE TO FUNCTIONALIZED NORBORNENES
  申请人：Bell Andrew

  公开号：US20090118539A1

  公开（公告）日：2009-05-07

  Embodiments in accordance with the present invention provide for forming essentially pure diastereomers of 5/6-substituted norbornene-type monomers. Further, embodiments in accordance with the present invention encompass polymerizing such diastereomers to form addition or ROMP polymers where a desired exo-/endo-ratio of the diastereomers is provided to the polymerization, such ratio designed to provide a desired ratio of endo-/exo-structured repeating units for a resulting polymer to have desired physical or chemical properties.

  根据本发明的实施例，提供形成基本纯的5/6-取代去氢莰烯型单体的异构体。此外，根据本发明的实施例涵盖聚合这种异构体以形成加成或ROMP聚合物，其中所提供给聚合反应的异构体的期望外/内比例设计为提供所得聚合物具有期望的物理或化学性质的外/内结构重复单元的期望比例。
• Norbornene-type polymers, compositions thereof and lithographic processes using such compositions
  申请人：Promerus LLC

  公开号：EP2031007A2

  公开（公告）日：2009-03-04

  A top-coat composition comprising a non-self imageable polymer consisting of norbornene-type repeating units, said polymer comprising a first norbornene-type repeating unit represented by Formula I: where X is -CH2-, -CH2CH2-, O or S; n is an integer from 0 to 5 inclusive; each of R1 to R4 independently represents hydrogen, a linear or branched alkyl group, or a linear or branched haloalkyl group, subject to the proviso that at least one of R1 to R4 is a -QNHSO2R5 group where Q is a linear or branched alkyl spacer of 1 to 5 carbons, and R5 is a perhalo group of 1 to 10 carbon atoms, a solvent and optionally comprising one or more of a crosslinking agent, an acidic material or a surfactant.

  一种面漆组合物，包含一种由降冰片烯型重复单元组成的非自显影聚合物，所述聚合物包含由式 I 表示的第一降冰片烯型重复单元： 其中 X 是-CH2-、- -、O 或 S；n 是 0 至 5（包括 5）的整数；R1 至 R4 中的每一个都独立地代表氢、直链或支链烷基或直链或支链卤代烷基，但 R1 至 R4 中至少有一个是-QNHSO2R5 基团，其中 Q 是 1 至 5 个碳原子的直链或支链烷基间隔物，R5 是 1 至 10 个碳原子的全卤基团，溶剂，并可选择包含一种或多种交联剂、酸性物质或表面活性剂。
• NORBORNENE-TYPE POLYMERS AND THEIR MANUFACTURE PROCESS
  申请人：Promerus LLC

  公开号：EP1853972B1

  公开（公告）日：2011-07-20
• Use of a Combination Chain Transfer and Activating Agent to Control Molecular Weight and Optical Density of Pd Catalyzed Norbornene Polymers
  申请人：Rhodes Larry F.

  公开号：US20080242810A1

  公开（公告）日：2008-10-02

  A method of controlling the molecular weight of poly(cyclic) olefin (norbornene-type) polymers and activating the polymerization thereof with a single material is provided. Such method include adding a chain transfer/activating agent to a mixture of monomer(s), catalyst, solvent and an optional cocatalyst and polymerizing the mixture to form a polymer. It is shown that the amount of chain transfer/activating agent in the mixture can serve to control the molecular weight of the resulting polymer, its percent conversion or both, and in some embodiments the optical density of the resulting polymer.
• Use Of A Combination Chain Transfer And Activating Agent To Control Molecular Weight And Optical Density Of Pd Catalyzed Norbornene Polymers
  申请人：Rhodes Larry F.

  公开号：US20110009578A1

  公开（公告）日：2011-01-13

  A method of controlling the molecular weight of poly(cyclic) olefin (norbornene-type) polymers and activating the polymerization thereof with a single material is provided. Such method include adding a chain transfer/activating agent to a mixture of monomer(s), catalyst, solvent and an optional cocatalyst and polymerizing the mixture to form a polymer. It is shown that the amount of chain transfer/activating agent in the mixture can serve to control the molecular weight of the resulting polymer, its percent conversion or both, and in some embodiments the optical density of the resulting polymer.