2,3,4,7-tetramethoxy-9,10-phenanthrenequinone | 873385-33-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: 2,3,4,7-tetramethoxy-9,10-phenanthrenequinone
• 英文别名: 2,3,4,7-tetramethoxy-phenanthrene-9,10-dione；2,3,4,7-Tetramethoxy-phenanthren-9,10-dion；2,3,4,7-Tetramethoxyphenanthrene-9,10-dione；2,3,4,7-tetramethoxyphenanthrene-9,10-dione
• CAS: 873385-33-2
• 化学式: C₁₈H₁₆O₆
• 分子量: 328.321
• InChiKey: BGMTYNWQXQXDCS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  24
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  71.1
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  2,3,4,7-tetramethoxy-9,10-phenanthrenequinone 、 邻苯二胺 在 甲醇 、 溶剂黄146 作用下， 生成 2,3,4,7-tetramethoxy-dibenzo[a,c]phenazine
  参考文献：
  名称：

  Oxidation of Gas Mixtures Containing Dimethyl Sulfide, Hydrogen Sulfide, and Methanethiol Using a Two-Stage Biotrickling Filter

  摘要：

  A biofiltration technique was developed for removing a mixture of hydrogen sulfide (H2S), methanethiol (MeSH), and dimethyl sulfide (Me2S) from waste gases. Since H2S, especially at high concentrations, disturbs the removal of Me2S, two biotrickling filters with different microbes and operating pH levels were connected in series to create a two-stage system. Different loads of these gases were studied in order to determine their impact on the removal capacity of the system. The microbial consortia for these filters were enriched from the sludge of a Finnish refinery with bubbling H2S or Me2S. Acclimation for Me2S took 2 weeks, though no acclimation time was needed for the other gases. The first filter, at a pH of 2, removed most of the H2S and some of the MeSH and Me2S. The second filter, at a pH of similar to6.5, removed the rest of the MeSH and most of the Me2S. The total maximum loads of the whole two-stage biotrickling filter were 1150 g/m(3)/day for H2S-S (suffix S indicates the results are counted as sulfur amounts), 879 g/m(3)/day for Me2S-S, and 66 g/m(3)/day for MeSH-S treated in a gas mixture. The average removal efficiencies for all gases tested were 99% or higher.

  DOI：

  10.1080/10473289.2001.10464260
• 作为产物：
  描述：

  1-(3-methoxyphenyl)-2-(3,4,5-trimethoxyphenyl)acetylene 在 potassium permanganate 、 四氯化钛 、 碳酸氢钠 、 magnesium sulfate 作用下， 以 二氯甲烷 、 水 、 丙酮 为溶剂， 反应 24.09h， 生成 2,3,4,7-tetramethoxy-9,10-phenanthrenequinone
  参考文献：
  名称：

  Synthesis of Highly Functionalized 9,10-Phenanthrenequinones by Oxidative Coupling Using MoCl₅

  摘要：

  The strong oxidative power of molybdenum pentachloride gives rise to an efficient oxidative C-C bond formation of benzil derivatives to the corresponding 9,10-phenanthrenequinones. A highly complementary method to previous approaches was developed. The required derivatives are accessible in a modular fashion and in excellent yields. By this approach the orchid-derived natural product cypripediquinone A was synthesized for the first time.

  DOI：

  10.1021/ol300948u

文献信息

• The Synthesis of Isocolchinol Methyl Ether
  作者：Henry Rapoport、Robert H. Allen、Merle E. Cisney

  DOI：10.1021/ja01608a039

  日期：1955.2.1
• Barton et al., Journal of the Chemical Society, 1949, p. 1079,1083
  作者：Barton et al.

  DOI：——

  日期：——
• The Synthesis of DL-Colchinol Methyl Ether^1,2
  作者：Henry Rapoport、Arthur R. Williams、Merle E. Cisney

  DOI：10.1021/ja01148a005

  日期：1951.4
• Synthesis of Highly Functionalized 9,10-Phenanthrenequinones by Oxidative Coupling Using MoCl₅
  作者：Simon Trosien、Siegfried R. Waldvogel

  DOI：10.1021/ol300948u

  日期：2012.6.15

  The strong oxidative power of molybdenum pentachloride gives rise to an efficient oxidative C-C bond formation of benzil derivatives to the corresponding 9,10-phenanthrenequinones. A highly complementary method to previous approaches was developed. The required derivatives are accessible in a modular fashion and in excellent yields. By this approach the orchid-derived natural product cypripediquinone A was synthesized for the first time.
• Oxidation of Gas Mixtures Containing Dimethyl Sulfide, Hydrogen Sulfide, and Methanethiol Using a Two-Stage Biotrickling Filter
  作者：Arja Ruokojärvi、Juhani Ruuskanen、Pertti J. Martikainen、Minna Olkkonen

  DOI：10.1080/10473289.2001.10464260

  日期：2001.1

  A biofiltration technique was developed for removing a mixture of hydrogen sulfide (H2S), methanethiol (MeSH), and dimethyl sulfide (Me2S) from waste gases. Since H2S, especially at high concentrations, disturbs the removal of Me2S, two biotrickling filters with different microbes and operating pH levels were connected in series to create a two-stage system. Different loads of these gases were studied in order to determine their impact on the removal capacity of the system. The microbial consortia for these filters were enriched from the sludge of a Finnish refinery with bubbling H2S or Me2S. Acclimation for Me2S took 2 weeks, though no acclimation time was needed for the other gases. The first filter, at a pH of 2, removed most of the H2S and some of the MeSH and Me2S. The second filter, at a pH of similar to6.5, removed the rest of the MeSH and most of the Me2S. The total maximum loads of the whole two-stage biotrickling filter were 1150 g/m(3)/day for H2S-S (suffix S indicates the results are counted as sulfur amounts), 879 g/m(3)/day for Me2S-S, and 66 g/m(3)/day for MeSH-S treated in a gas mixture. The average removal efficiencies for all gases tested were 99% or higher.