3,4,5-tris(pentyloxy)benzaldehyde | 1187649-60-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 3,4,5-tris(pentyloxy)benzaldehyde
• 英文别名: 3,4,5-Tripentoxybenzaldehyde
• CAS: 1187649-60-0
• 化学式: C₂₂H₃₆O₄
• 分子量: 364.525
• InChiKey: KTXFNXKMOXAESR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.7
• 重原子数：
  26
• 可旋转键数：
  16
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.68
• 拓扑面积：
  44.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  3,4,5-tris(pentyloxy)benzaldehyde 、 4-氨基苯甲酰肼 在 溶剂黄146 作用下， 以 乙醇 为溶剂， 反应 12.0h， 生成
  参考文献：
  名称：

  Tuning the thermotropic properties of liquid crystalline p-substituted aroylhydrazones

  摘要：

  通过改变周边烷氧链密度，在p-取代芳酰肼中观察到片层烟酸A到柱状介晶相的交叉。

  DOI：

  10.1039/c5ra06620d
• 作为产物：
  描述：

  没食子酸乙酯 在 manganese(IV) oxide 、 lithium aluminium tetrahydride 、 potassium carbonate 作用下， 以 四氢呋喃 、 氯仿 、 N,N-二甲基甲酰胺 为溶剂， 生成 3,4,5-tris(pentyloxy)benzaldehyde
  参考文献：
  名称：

  Room Temperature Liquid Porphyrins

  摘要：

  报道了5,10,15,20-四(3,4,5-三烷氧基苯基)卟啉的合成，这些化合物在室温下表现出流态行为。热物性和流变学测量表明，它们在25°C（298 K）时表现得像液体。

  DOI：

  10.1246/cl.2010.714

文献信息

• LIQUID PORPHYRIN DERIVATIVE, AND METHOD FOR PRODUCING THE SAME
  申请人：Maruyama Sumio

  公开号：US20110046366A1

  公开（公告）日：2011-02-24

  The present invention is to provide a liquid porphyrin derivative at 25° C. and at temperatures from 26 to 40° C., and a method for producing the same. The liquid porphyrin derivative of the present invention is represented by the following formula (1): wherein M represents 2H (hydrogen atoms) or an atom or compound capable of binding covalently or coordinately to tetraphenylporphyrin; each of R 1 , R 2 , and R 3 independently represents a hydrogen atom, or an alkoxy group having 7 to 14 or 15 carbon atoms represented by OR 4 ; R 4 represents a substituted or unsubstituted alkyl group having 7 to 14 or 15 carbon atoms; and all the R 1 s, all the R 2 s, and all the R 3 s are respectively the same; and there are cases where the R 2 s and the R 3 s are the alkoxy groups having 7 to 14 or 15 carbon atoms represented by OR 4 , and the R 1 s are hydrogen atoms, where the R 1 s and the R 3 s are the alkoxy groups having 7 to 14 or 15 carbon atoms represented by OR 4 , and the R 2 s are hydrogen atoms, where the R 1 s and the R 2 s are the alkoxy groups having 7 to 14 or 15 carbon atoms represented by OR 4 , and the R 3 s are hydrogen atoms, and where the R 1 s, the R 2 s and the R 3 s are the alkoxy groups having 7 to 14 or 15 carbon atoms represented by OR 4 .

  本发明提供了一种在25℃和26℃至40℃温度下的液态卟吩衍生物以及其制备方法。本发明的液态卟吩衍生物由以下式子（1）表示：其中M代表2H（氢原子）或能够共价或配位地结合四苯基卟吩的原子或化合物；每个R1、R2和R3独立地表示氢原子，或由OR4表示的具有7至14或15个碳原子的烷氧基；R4表示具有7至14或15个碳原子的取代或未取代的烷基基团；所有的R1、所有的R2和所有的R3分别相同；有时R2和R3是由OR4表示的具有7至14或15个碳原子的烷氧基，而R1是氢原子；或者R1和R3是由OR4表示的具有7至14或15个碳原子的烷氧基，而R2是氢原子；或者R1和R2是由OR4表示的具有7至14或15个碳原子的烷氧基，而R3是氢原子；或者R1、R2和R3均为由OR4表示的具有7至14或15个碳原子的烷氧基。
• CHALCONE DERIVATIVE COMPOUNDS
  申请人：NIPPON OIL AND FATS COMPANY, LIMITED

  公开号：EP0328669A1

  公开（公告）日：1989-08-23

  Chalcone derivative compounds represented by general formula (I) or (II), wherein R₁ and R₂ each represents a ha­logen atom, a hydroxy group, an amino group, a dimethylamino group, a nitro group, a cyano group, a phenyl group, an acetyl group, an alkyl group containing 1 to 18 carbon atoms or an alkyloxy group containing 1 to 22 carbon atoms, n₁ and n₂ each represents an integer of 0 to 21, and m₁ and m₂ each represents an integer of 0 to 5.

  通式(I)或(II)代表的查耳酮衍生物化合物，其中 R₁ 和 R₂ 各自代表卤素原子、羟基、氨基、二甲基氨基、硝基、氰基、苯基、乙酰基、含 1 至 18 个碳原子的烷基或含 1 至 22 个碳原子的烷氧基，n₁ 和 n₂ 各自代表整数、乙酰基、含 1 至 18 个碳原子的烷基或含 1 至 22 个碳原子的烷氧基，n₁ 和 n₂ 各自代表 0 至 21 的整数，m₁ 和 m₂ 各自代表 0 至 5 的整数。
• LIQUID PORPHYRIN DERIVATIVE AND METHOD FOR PRODUCING THE SAME
  申请人：Dai Nippon Printing Co., Ltd.

  公开号：EP2253634A1

  公开（公告）日：2010-11-24

  The present invention is to provide a liquid porphyrin derivative at 25 °C and at temperatures from 26 to 40 °C, and a method for producing the same. The liquid porphyrin derivative of the present invention is represented by the following formula (1): wherein M represents 2H (hydrogen atoms) or an atom or compound capable of binding covalently or coordinately to tetraphenylporphyrin; each of R1, R2, and R3 independently represents a hydrogen atom, or an alkoxy group having 7 to 14 or 15 carbon atoms represented by OR4; R4 represents a substituted or unsubstituted alkyl group having 7 to 14 or 15 carbon atoms; and all the R1s, all the R2s, and all the R3s are respectively the same; and there are cases where the R2s and the R3s are the alkoxy groups having 7 to 14 or 15 carbon atoms represented by OR4, and the R1s are hydrogen atoms, where the R1s and the R3s are the alkoxy groups having 7 to 14 or 15 carbon atoms represented by OR4, and the R2s are hydrogen atoms, where the R1s and the R2s are the alkoxy groups having 7 to 14 or 15 carbon atoms represented by OR4, and the R3s are hydrogen atoms, and where the R1s, the R2s and the R3s are the alkoxy groups having 7 to 14 or 15 carbon atoms represented by OR4.

  本发明旨在提供一种在 25℃和 26 至 40℃温度下的液态卟啉衍生物及其生产方法。本发明的液态卟啉衍生物由下式（1）表示： 其中 M 代表 2H（氢原子）或能与四苯基卟啉共价结合或配位结合的原子或化合物； R1、R2 和 R3 各自独立地代表氢原子或由 OR4 代表的具有 7 至 14 或 15 个碳原子的烷氧基； R4 代表具有 7 至 14 或 15 个碳原子的取代或未取代的烷基；且所有 R1、所有 R2 和所有 R3 分别相同；在某些情况下，R2s 和 R3s 是由 OR4 表示的具有 7 至 14 或 15 个碳原子的烷氧基，而 R1s 是氢原子，其中 R1s 和 R3s 是由 OR4 表示的具有 7 至 14 或 15 个碳原子的烷氧基、R2s 为氢原子，其中 R1s 和 R2s 为具有 7 至 14 或 15 个碳原子的烷氧基，由 OR4 表示，R3s 为氢原子，其中 R1s、R2s 和 R3s 为具有 7 至 14 或 15 个碳原子的烷氧基，由 OR4 表示。
• Tuning the thermotropic properties of liquid crystalline p-substituted aroylhydrazones
  作者：Hemant Kumar Singh、Sachin Kumar Singh、Rajib Nandi、Madan Kumar Singh、Vijay Kumar、Ranjan K. Singh、D. S. Shankar Rao、S. Krishna Prasad、Bachcha Singh

  DOI：10.1039/c5ra06620d

  日期：——

  Lamellar smectic A to columnar mesophase crossover is observed in p-substituted aroylhydrazones by variation of the alkoxy chain density at peripherals.

  通过改变周边烷氧链密度，在p-取代芳酰肼中观察到片层烟酸A到柱状介晶相的交叉。
• Room Temperature Liquid Porphyrins
  作者：Sumio Maruyama、Kenta Sato、Hiroyuki Iwahashi

  DOI：10.1246/cl.2010.714

  日期：2010.7.5

  The syntheses of 5,10,15,20-tetrakis(3,4,5-trialkoxyphenyl)porphyrins, which exhibit fluid state behavior at room temperature, are reported. The thermal and rheological measurements indicate that they behave like liquid at 25 °C (298 K).

  报道了5,10,15,20-四(3,4,5-三烷氧基苯基)卟啉的合成，这些化合物在室温下表现出流态行为。热物性和流变学测量表明，它们在25°C（298 K）时表现得像液体。