7-Dodecyl-18-(4-methoxyphenyl)-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(23),2,4,9,11,13,15,20(24),21,25-decaene-6,8,17,19-tetrone | 1224438-43-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: 7-Dodecyl-18-(4-methoxyphenyl)-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(23),2,4,9,11,13,15,20(24),21,25-decaene-6,8,17,19-tetrone
• CAS: 1224438-43-0
• 化学式: C₄₃H₄₀N₂O₅
• 分子量: 664.801
• InChiKey: GIOYHXNBVULOSI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.8
• 重原子数：
  50
• 可旋转键数：
  13
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.3
• 拓扑面积：
  84
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  3,4,9,10-苝四羧酸二酐 在 咪唑 作用下， 以 甲醇 为溶剂， 反应 12.0h， 生成 7-Dodecyl-18-(4-methoxyphenyl)-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(23),2,4,9,11,13,15,20(24),21,25-decaene-6,8,17,19-tetrone
  参考文献：
  名称：

  Folding of two-dimensional nanoparticle superlattices enabled by emulsion-confined supramolecular co-assembly

  摘要：

  利用苝酞二酰亚胺分子和金纳米颗粒的共同组装，能够制备出折叠的二维纳米颗粒超晶格。

  DOI：

  10.1039/d2cc00330a

文献信息

• SENSOR COMPOUNDS AND ASSOCIATED METHODS AND DEVICES
  申请人：UNIVERSITY OF UTAH RESEARCH FOUNDATION

  公开号：US20180201612A1

  公开（公告）日：2018-07-19

  Methods of detecting a non-explosive analyte can include exposing a sensor compound to a non-explosive analyte and displaying a change in the sensor compound upon exposure of the sensor compound to the non-explosive analyte. A variety of sensor compounds for detecting a target analyte, including both explosive and non-explosive analytes, is also described. Sensor devices for detecting a target analyte can include a substrate and a sensor compound positioned on the substrate in a plurality of detection zones.

  检测非爆炸性分析物的方法可以包括将传感器化合物暴露于非爆炸性分析物，并在传感器化合物暴露于非爆炸性分析物时显示传感器化合物的变化。还描述了用于检测目标分析物（包括爆炸性和非爆炸性分析物）的各种传感器化合物。用于检测目标分析物的传感器设备可以包括底板和位于底板上的传感器化合物，其位于多个检测区域中。
• Ultrathin n-Type Organic Nanoribbons with High Photoconductivity and Application in Optoelectronic Vapor Sensing of Explosives
  作者：Yanke Che、Xiaomei Yang、Guilin Liu、Chun Yu、Hongwei Ji、Jianmin Zuo、Jincai Zhao、Ling Zang

  DOI：10.1021/ja909797q

  日期：2010.4.28

  Well-defined ultrathin nanoribbons have been fabricated from an amphiphilic electron donor acceptor (D-A) supramolecule comprising perylene tetracarboxylic diimide as the backbone scaffold to enforce the one-dimensional intermolecular assembly via strong a-stacking. These nanoribbons demonstrated high photoconductivity upon illumination with white light. The high photoconductivity thus obtained is likely due to the optimal molecular design that enables a good kinetic balance between the two competitive processes, the intramolecular charge recombination (between D and A) and the intermolecular charge transport along the nanoribbon. The photoconduction response has also proven to be prompt and reproducible with the light turning on and off. The photogenerated electrons within the nanoribbon can be efficiently trapped by the adsorbed oxygen molecules or other oxidizing species, leading to depletion of the charge carriers (and thus the electrical conductivity) of the nanoribbon, as typically observed for n-type semiconductor materials as applied in chemiresistors. Combination of this sensitive modulation of conductivity with the unique features intrinsic to the nanoribbon morphology (large surface area and continuous nanoporosity when deposited on a substrate to form a fibril film) enables efficient vapor sensing of nitro-based explosives.
• [EN] PHOTOCONDUCTIVE SENSOR MATERIALS FOR DETECTION OF EXPLOSIVE VAPOR<br/>[FR] MATÉRIAUX PHOTOCONDUCTEURS DE CAPTEURS UTILISÉS DANS LA DÉTECTION DE VAPEUR EXPLOSIVE
  申请人：UNIV UTAH

  公开号：WO2011079296A3

  公开（公告）日：2011-12-01
• [EN] SENSOR COMPOUNDS AND ASSOCIATED METHODS AND DEVICES<br/>[FR] COMPOSÉS DE DÉTECTION ET PROCÉDÉS ET DISPOSITIFS ASSOCIÉS
  申请人：UNIV UTAH RES FOUND

  公开号：WO2017008074A1

  公开（公告）日：2017-01-12

  Methods of detecting a non-explosive analyte can include exposing a sensor compound to a non-explosive analyte and displaying a change in the sensor compound upon exposure of the sensor compound to the non-explosive analyte. A variety of sensor compounds for detecting a target analyte, including both explosive and non-explosive analytes, is also described. Sensor devices for detecting a target analyte can include a substrate and a sensor compound positioned on the substrate in a plurality of detection zones.