2-(4-(dimethylamino)phenyl)-9-dodecylanthra[2,1,9-def:6,5,10-d'e'f']diisoquinoline-1,3,8,10(2H,9H)-tetraone | 1224438-44-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: 2-(4-(dimethylamino)phenyl)-9-dodecylanthra[2,1,9-def:6,5,10-d'e'f']diisoquinoline-1,3,8,10(2H,9H)-tetraone
• CAS: 1224438-44-1
• 化学式: C₄₄H₄₃N₃O₄
• 分子量: 677.843
• InChiKey: KSBSAYZGGZHVND-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.12
• 重原子数：
  51.0
• 可旋转键数：
  13.0
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.32
• 拓扑面积：
  78.0
• 氢给体数：
  0.0
• 氢受体数：
  5.0

反应信息

• 作为产物：
  描述：

  3,4,9,10-苝四羧酸二酐 在 咪唑 、 potassium hydroxide 作用下， 生成 2-(4-(dimethylamino)phenyl)-9-dodecylanthra[2,1,9-def:6,5,10-d'e'f']diisoquinoline-1,3,8,10(2H,9H)-tetraone
  参考文献：
  名称：

  1D nanofiber composites of perylene diimides for visible-light-driven hydrogen evolution from water

  摘要：

  自组装的供体-受体型苝二酰亚胺1D纳米纤维已被用于在可见光照射下从水裂解中光催化产生H2。

  DOI：

  10.1039/c4ra09258a

文献信息

• Ultrathin n-Type Organic Nanoribbons with High Photoconductivity and Application in Optoelectronic Vapor Sensing of Explosives
  作者：Yanke Che、Xiaomei Yang、Guilin Liu、Chun Yu、Hongwei Ji、Jianmin Zuo、Jincai Zhao、Ling Zang

  DOI：10.1021/ja909797q

  日期：2010.4.28

  Well-defined ultrathin nanoribbons have been fabricated from an amphiphilic electron donor acceptor (D-A) supramolecule comprising perylene tetracarboxylic diimide as the backbone scaffold to enforce the one-dimensional intermolecular assembly via strong a-stacking. These nanoribbons demonstrated high photoconductivity upon illumination with white light. The high photoconductivity thus obtained is likely due to the optimal molecular design that enables a good kinetic balance between the two competitive processes, the intramolecular charge recombination (between D and A) and the intermolecular charge transport along the nanoribbon. The photoconduction response has also proven to be prompt and reproducible with the light turning on and off. The photogenerated electrons within the nanoribbon can be efficiently trapped by the adsorbed oxygen molecules or other oxidizing species, leading to depletion of the charge carriers (and thus the electrical conductivity) of the nanoribbon, as typically observed for n-type semiconductor materials as applied in chemiresistors. Combination of this sensitive modulation of conductivity with the unique features intrinsic to the nanoribbon morphology (large surface area and continuous nanoporosity when deposited on a substrate to form a fibril film) enables efficient vapor sensing of nitro-based explosives.