3,4-bis(2-(2-(pent-4-en-1-yloxy)ethoxy)ethoxy)benzonitrile | 947193-15-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 3,4-bis(2-(2-(pent-4-en-1-yloxy)ethoxy)ethoxy)benzonitrile
• CAS: 947193-15-9
• 化学式: C₂₅H₃₇NO₆
• 分子量: 447.572
• InChiKey: NDMSOOCHLVGNCT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.31
• 重原子数：
  32.0
• 可旋转键数：
  22.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.56
• 拓扑面积：
  79.17
• 氢给体数：
  0.0
• 氢受体数：
  7.0

反应信息

• 作为反应物：
  描述：

  3,4-bis(2-(2-(pent-4-en-1-yloxy)ethoxy)ethoxy)benzonitrile 在 lithium aluminium tetrahydride 作用下， 以 四氢呋喃 为溶剂， 反应 12.0h， 以78%的产率得到(3,4-bis(2-(2-(pent-4-en-1-yloxy)ethoxy)ethoxy)phenyl)methanamine
  参考文献：
  名称：

  Bifunctional [c2]Daisy-Chains and Their Incorporation into Mechanically Interlocked Polymers

  摘要：

  A strategy for the formation of mechanically interlocked polymers is presented. Ring-closing olefin metathesis has been shown to provide a very high yielding route to [c2]daisy-chains suitably functionalized to allow their one-step conversion to bisolefins which can be used as monomers in ADMET polymerizations to afford mechanically interlocked polymers. Metathesis, in two different guises is making a hitherto unreachable goal in synthesis a reality.

  DOI：

  10.1021/ja0725100
• 作为产物：
  描述：

  2-(2-(pent-4-enyloxy)ethoxy)ethanol 在 potassium carbonate 、 三乙胺 作用下， 以 二氯甲烷 、 N,N-二甲基甲酰胺 为溶剂， 反应 72.0h， 生成 3,4-bis(2-(2-(pent-4-en-1-yloxy)ethoxy)ethoxy)benzonitrile
  参考文献：
  名称：

  Bifunctional [c2]Daisy-Chains and Their Incorporation into Mechanically Interlocked Polymers

  摘要：

  A strategy for the formation of mechanically interlocked polymers is presented. Ring-closing olefin metathesis has been shown to provide a very high yielding route to [c2]daisy-chains suitably functionalized to allow their one-step conversion to bisolefins which can be used as monomers in ADMET polymerizations to afford mechanically interlocked polymers. Metathesis, in two different guises is making a hitherto unreachable goal in synthesis a reality.

  DOI：

  10.1021/ja0725100