Cp*RuCl(isoprene) | 148657-53-8

• 分子结构分类: 有机化合物 - 碳氢化合物
• 英文名称: Cp*RuCl(isoprene)
• 英文别名: chlororuthenium(1+);2-methylbuta-1,3-diene;1,2,3,4,5-pentamethylcyclopenta-1,3-diene
• CAS: 148657-53-8
• 化学式: C₅H₈*C₁₀H₁₅*Cl*Ru
• 分子量: 339.871
• InChiKey: ZIEIIYRIAYRXRD-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  1.7
• 重原子数：
  17.0
• 可旋转键数：
  1.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  Cp*RuCl(isoprene) 、 (S)-(2-aminopropyl)diphenylphosphine 以 二氯甲烷 为溶剂， 生成
  参考文献：
  名称：

  A Convenient Method for the Synthesis of Protic 2-(Tertiary phosphino)-1-amines and Their Cp*RuCl Complexes

  摘要：

  A variety of protic 2-(tertiary phosphino)-1-amines (R2PCH2CHR'NHR '', P-NH) have been prepared from 2-ox-azolidinones and secondary phosphines using a newly developed acid-promoted decarboxylative C-P bond formation reaction. Treatment of the resulting chiral P-NH compounds with Cp*RuCl(isoprene) in CH2Cl2 smoothly furnished chiral Cp*RuCl(P-NH) complexes with a typical three-legged piano-stool structure, which prove to be excellent catalyst precursors for asymmetric reactions, including the isomerization of allylic alcohols and hydrogenation of imides.

  DOI：

  10.1021/om801042b

文献信息

• Highly Efficient Chemoselective Hydrogenolysis of Epoxides Catalyzed by a (η⁵-C₅(CH₃)₅)Ru Complex Bearing a 2-(Diphenylphosphino)ethylamine Ligand
  作者：Masato Ito、Makoto Hirakawa、Akihide Osaku、Takao Ikariya

  DOI：10.1021/om034006j

  日期：2003.10.1

  Terminal epoxides are hydrogenolyzed to give secondary alcohols with high regioselectivity using the ternary catalyst system of Cp*RuCl(cod)-2-(diphenyl-phosphino)ethylamine (1a)-KOH (CP* = eta(5)-C-5(CH3)(5), cod = 1,5-cyclooctadiene) in 2-propanol under mild conditions.
• (Acetonitrile-<i>N</i>)(η⁴-2-methylbuta-1,3-diene)(η⁵-pentamethylcyclopentadienyl)ruthenium(II) trifluoromethanesulfonate
  作者：C. Gemel、K. Kirchner、R. Schmid、K. Mereiter

  DOI：10.1107/s0108270199012342

  日期：1999.12.15

  The title compound, [Rueta(5)-C-5(CH3)(5)}eta(4)-CH2C(CH3)CHCH2}(CH3CN)](CF3SO3) or [Ru(C5H8)(C10H15)(C2H3N)](CF3SO3), contains a half-sandwich ruthenium complex with an exo-oriented pi-bonded diene moiety inclined at an angle of 16.0(2)degrees to the cyclopentadienyl ring. The coordination geometry of ruthenium can be described as a three-legged piano stool.