N,N-bis(2-ethyl-5-methyl-imidazolyl-4-methyl)aminomethane | 656238-94-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: N,N-bis(2-ethyl-5-methyl-imidazolyl-4-methyl)aminomethane
• 英文别名: 1-(2-ethyl-5-methyl-1H-imidazol-4-yl)-N-[(2-ethyl-5-methyl-1H-imidazol-4-yl)methyl]-N-methylmethanamine
• CAS: 656238-94-7
• 化学式: C₁₅H₂₅N₅
• 分子量: 275.397
• InChiKey: QOAOJNRRNHCUJF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  20
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  60.6
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  甲醇 、 copper(II) choride dihydrate 、 N,N-bis(2-ethyl-5-methyl-imidazolyl-4-methyl)aminomethane 以 甲醇 、 水 为溶剂， 生成 [Cu(N,N-bis(2-ethyl-5-methyl-imidazolyl-4-methyl)aminomethane)Cl2]*MeOH
  参考文献：
  名称：

  Copper(II) compounds of some Mannich-condensation amine–bis-imidazole ligands

  摘要：

  The Mannich condensation of formaldehyde with some amines and imidazoles rendered four bis-imidazole ligands in a very simple one pot reaction. The X-ray structures of four copper(II) compounds, obtained with these ligands, show in all cases the copper(II) ions to be in a square pyramidal environment. Three compounds appeared to be mononuclear, while the least bulky ligand rendered a dinuclear complex. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(03)00224-x

文献信息

• Copper(II) compounds of some Mannich-condensation amine–bis-imidazole ligands
  作者：Willem L Driessen、Daniëlle Rehorst、Jan Reedijk、Ilpo Mutikainen、Urho Turpeinen

  DOI：10.1016/s0020-1693(03)00224-x

  日期：2003.11

  The Mannich condensation of formaldehyde with some amines and imidazoles rendered four bis-imidazole ligands in a very simple one pot reaction. The X-ray structures of four copper(II) compounds, obtained with these ligands, show in all cases the copper(II) ions to be in a square pyramidal environment. Three compounds appeared to be mononuclear, while the least bulky ligand rendered a dinuclear complex. (C) 2003 Elsevier B.V. All rights reserved.