环己酮与甲醛的反应产物 | 94891-38-0

• 分子结构分类: 有机化合物 - 有机氧化合物
• 中文名称: 环己酮与甲醛的反应产物
• 英文名称: Cyclohexanone;formaldehyde
• CAS: 94891-38-0
• 化学式: C7H12O2
• 分子量: 128.17
• InChiKey: CJTRGWNHVKRZEB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.33
• 重原子数：
  9
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  34.1
• 氢给体数：
  0
• 氢受体数：
  2

文献信息

• Asymmetrically substituted phosphinic acids
  申请人：Bauer Harald

  公开号：US20080214708A1

  公开（公告）日：2008-09-04

  The invention relates to asymmetrically substituted phosphinic acids of the formula (I) R 1 R 2 C(OH)—P(═O)(OX)—C(OH)R 3 R 4 (I) in which X is hydrogen R 1 , R 2 , R 3 , and R 4 are identical or different and are hydrogen, alkyl, alkenyl, alkynyl, aralkyl, aryl and/or alkaryl, with the proviso that the respective R 1 R 2 C(OH)— and —C(OH)R 3 R 4 groups are always different, to a process for their preparation, and to their use.

  该发明涉及公式（I）中不对称取代的膦酸，其中X为氢，R1、R2、R3和R4相同或不同，可以是氢、烷基、烯基、炔基、芳基、芳基烷基和/或烷基芳基，但要求相应的R1R2C（OH）-和-C（OH）R3R4基始终不同，以及其制备方法和用途。
• Epoxidgruppenhaltige modifizierte Acetophenon-Formaldehyd-Harze
  申请人：CIBA-GEIGY AG

  公开号：EP0356391A2

  公开（公告）日：1990-02-28

  Polyglycidylether, die dadurch erhältlich sind, dass man Acetophenon mit 0,7 bis 1,4 Mol Formaldehyd pro Mol Acetophenon in Gegenwart eines alkalischen Katalysators bei einer Temperatur von 50-100°C zu einem carbonylgruppenhaltigen Acetophenon-Formaldehyd-Harz umsetzt, das carbonylgruppenhaltige Harz zu einem modifizierten hydroxylgruppenhal­tigen Acetophenon-Formaldehyd-Harz hydriert, dieses Harz anschliessend mit Epichlorhydrin in Gegenwart eines Phasentransferkatalysators in den entsprechenden Polychlorhydrinether überführt, und diesen mit einer Base dehydrochloriert, eignen sich als Epoxidharze, z.B. für die Herstellung von Pulverlacken mit guter Chemiekalienbeständigkeit und Adhäsion.

  聚缩水甘油醚：在碱性催化剂存在下，在 50-100°C 的温度下，使苯乙酮与每摩尔苯乙酮中 0.7-1.4 摩尔的甲醛反应，得到含羰基的苯乙酮甲醛树脂、将含羰基的树脂氢化为改性的含羟基的苯乙酮甲醛树脂，然后在相转移催化剂存在下用环氧氯丙烷将该树脂转化为相应的聚氯醇醚，并用碱对后者进行脱氯。它们适合用作环氧树脂，例如用于生产具有良好耐化学性和附着力的粉末涂料。
• Castor oil based polyurethane for bridge decking and related applications
  申请人：W.R. Grace & Co.-Conn.

  公开号：EP0361170A2

  公开（公告）日：1990-04-04

  Novel polyurethane formulations especially useful as membranes for the protection of bridge deckings. The polyurethane is prepared by mixing two components, A and B. Component A comprises castor oil modified with a ketone-formaldehyde condensate and also preferably contains an elastomer. Component B is a modified MDI, being a mixture of diphenylmethane diisocyanate and its reaction product with a low molecular weight poly(oxyalkylene).

  新型聚氨酯配方特别适用于桥面保护膜。A 组分包括用酮-甲醛缩合物改性的蓖麻油，最好还含有一种弹性体。B 组分是改性 MDI，是二苯基甲烷二异氰酸酯及其与低分子量聚（氧烷基）反应产物的混合物。
• Castor oil based polyurethane for underbody coatings and the like
  申请人：W.R. Grace & Co.-Conn.

  公开号：EP0364738A1

  公开（公告）日：1990-04-25

  Two component polyol/polyisocyanate composition useful in forming an abrasion resistant polyurethane automotive undercoating. The polyol component is unmodified castor oil or castor oil modified with cyclohexanone-formaldehyde condensate. The modified castor oil may be further modified by adding the reaction product of neopentyl glycol and adipic acid. The polyisocyanate component comprises an MDI-based mixture containing polyisocyanate prepolymers based on alkylene oxides.

  双组分多元醇/聚异氰酸酯组合物可用于形成耐磨的聚氨酯汽车底漆。多元醇成分是未经改性的蓖麻油或用环己酮-甲醛缩合物改性的蓖麻油。改性蓖麻油可通过加入新戊二醇和己二酸的反应产物进一步改性。多异氰酸酯组分包括一种以 MDI 为基础的混合物，其中含有以氧化烯为基础的多异氰酸酯预聚物。
• Polyurethane encapsulated fertilizer having improved slow-release properties
  申请人：Bayer Corporation

  公开号：EP1106635A2

  公开（公告）日：2001-06-13

  The present invention relates to polyurethane encapsulated fertilizer particles which exhibit slow-release properties and to a process for their production. The process comprises applying an isocyanate-reactive component to fertilizer particles, to form fertilizer particles coated with an isocyanate-reactive component, applying a polyisocyanate component onto the coated fertilizer particles to form polyurethane encapsulated fertilizer particles, and, optionally, repeating these steps as many times as necessary to form the polyurethane encapsulated fertilizer particles that contain about 2 to 20% by weight of polyurethane, based on the total weight of the encapsulated fertilizer particles. Suitable isocyanate-reactive components include polyesterether polyols that comprise either a blend of or the reaction product of (i) castor oil having an OH number of about 160 to about 170, a viscosity of about 500 to about 900 mPa·s at 25°C, and a water content of less than 0.5% by weight; and (ii) a polyether polyol having an OH number of from 28 to 700, a functionality of from 3 to 8, and a molecular weight of about 240 to about 6,000, and a viscosity of from about 50 to 35,000 mPa·s at 25°C. The polyether polyol must be prepared from a suitable initiator compound and an alkylene oxide comprising at least 70% by weight of propylene oxide.

  本发明涉及具有缓释特性的聚氨酯封装肥料颗粒及其生产工艺。该工艺包括将异氰酸酯反应组分涂覆在肥料颗粒上，形成涂覆有异氰酸酯反应组分的肥料颗粒，将聚异氰酸酯组分涂覆在涂覆的肥料颗粒上，形成聚氨酯包封的肥料颗粒，并可选择地根据需要多次重复这些步骤，以形成聚氨酯包封的肥料颗粒，根据包封的肥料颗粒的总重量，该颗粒含有约 2%至 20%（按重量计）的聚氨酯。合适的异氰酸酯反应组分包括聚酯醚多元醇，它包括以下物质的混合物或反应产物：(i) OH 数约为 160 至约 170、25°C 时粘度约为 500 至约 900 mPa-s、水含量小于 0.(ii)聚醚多元醇，其羟基数为 28 至 700，官能度为 3 至 8，分子量为 240 至 6,000 左右，25°C 时的粘度为 50 至 35,000 mPa-s。聚醚多元醇必须由合适的引发剂化合物和环氧丙烷（按重量计至少占 70%）制备。