[Pd(3-(1,2,2-trimethylpropyl)-1,10-phenanthroline)(CF3COO)2] | 419574-84-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: [Pd(3-(1,2,2-trimethylpropyl)-1,10-phenanthroline)(CF3COO)2]
• CAS: 419574-84-8
• 化学式: C₂₂H₂₀F₆N₂O₄Pd
• 分子量: 596.822
• InChiKey: QGTQBHFWZHCURU-CSIATVMVSA-L

反应信息

• 作为反应物：
  描述：

  sodium hexaflorophosphate 、 (-)-(S)-3-(1,2,2-trimethylpropyl)-1,10-phenanthroline 、 [Pd(3-(1,2,2-trimethylpropyl)-1,10-phenanthroline)(CF3COO)2] 以 甲醇 为溶剂， 以65%的产率得到[Pd((S)-3-(1,2,3-trimethylpropyl)-1,10-phenanthroline)2][PF6]2
  参考文献：
  名称：

  Very Stable Palladium(II)−(N−N) Catalysts for the Synthesis of High-Molecular-Weight CO/Styrene Polyketones

  摘要：

  A dicationic (N-N) bis-chelated Pd(II) complex containing the 3-alkyl-substituted 1, 10-phenanthroline 1 as the unique ligand provides exceptionally high productivities in CO/styrene copolymerization, giving a polymer of unprecedentedly high molecular weight.

  DOI：

  10.1021/om011020s
• 作为产物：
  描述：

  三氟乙酸 、 palladium diacetate 、 (-)-(S)-3-(1,2,2-trimethylpropyl)-1,10-phenanthroline 以 甲醇 为溶剂， 以55%的产率得到[Pd(3-(1,2,2-trimethylpropyl)-1,10-phenanthroline)(CF3COO)2]
  参考文献：
  名称：

  Very Stable Palladium(II)−(N−N) Catalysts for the Synthesis of High-Molecular-Weight CO/Styrene Polyketones

  摘要：

  A dicationic (N-N) bis-chelated Pd(II) complex containing the 3-alkyl-substituted 1, 10-phenanthroline 1 as the unique ligand provides exceptionally high productivities in CO/styrene copolymerization, giving a polymer of unprecedentedly high molecular weight.

  DOI：

  10.1021/om011020s