| 443287-27-2

• CAS: 443287-27-2
• 化学式: C₆₈H₈₈Cu₂O₄S₄
• 分子量: 1224.8
• InChiKey: HVJYERYEFPKNNN-UHFFFAOYSA-J

反应信息

• 作为反应物：
  描述：

  吡啶 、 以 二氯甲烷 为溶剂， 以26%的产率得到
  参考文献：
  名称：

  Mono- and dinuclear (o-thioetherphenolato)-copper(II) complexes. Structural models for galactose oxidase

  摘要：

  Three new o-thioetherphenol ligands have been synthesized: 1,2-bis(3,5-di-tert-butyl-2-hydroxyphenylsulfanyl)ethane (H(2)bse), 1,2-bis (3,5-di-tert-butyl-2-hydroxyphenylsulfanyl)benzene (H(2)bsb), and 4,6-di-tert-butyl-2-phenylsulfanylphenol (Hpsp). Their complexes with copper(II) were prepared and investigated by UV-Vis-, EPR-spectroscopy, their electro- and magnetochemistry have also been studied: [Cu-II(psp)(2)] (1). [Cu-2(II)(bse)(2)] (2), [Cu-2(II)(bsb)(2)] (3), [Cu-II(bsb)(py)(2)] (4). The crystal structures of the ligands H(2)bse, H(2)bsb, Hpsp and of the complexes 1, 2, 3, 4 have been determined by X-ray crystallography. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(01)00756-3
• 作为产物：
  描述：

  copper(l) chloride 、 1,2-bis(3,5-di-tert-butyl-2-hydroxyphenylsulfanyl)benzene 在 air 、 Et₃N 作用下， 以 四氢呋喃 为溶剂， 以29%的产率得到
  参考文献：
  名称：

  Mono- and dinuclear (o-thioetherphenolato)-copper(II) complexes. Structural models for galactose oxidase

  摘要：

  Three new o-thioetherphenol ligands have been synthesized: 1,2-bis(3,5-di-tert-butyl-2-hydroxyphenylsulfanyl)ethane (H(2)bse), 1,2-bis (3,5-di-tert-butyl-2-hydroxyphenylsulfanyl)benzene (H(2)bsb), and 4,6-di-tert-butyl-2-phenylsulfanylphenol (Hpsp). Their complexes with copper(II) were prepared and investigated by UV-Vis-, EPR-spectroscopy, their electro- and magnetochemistry have also been studied: [Cu-II(psp)(2)] (1). [Cu-2(II)(bse)(2)] (2), [Cu-2(II)(bsb)(2)] (3), [Cu-II(bsb)(py)(2)] (4). The crystal structures of the ligands H(2)bse, H(2)bsb, Hpsp and of the complexes 1, 2, 3, 4 have been determined by X-ray crystallography. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(01)00756-3