cis-[3,5-bis(4-n-hexadecyloxyphenyl)-1-(pyridin-2-yl)-1H-pyrazole]PdCl2 | 583032-68-2

• 英文名称: cis-[3,5-bis(4-n-hexadecyloxyphenyl)-1-(pyridin-2-yl)-1H-pyrazole]PdCl2
• CAS: 583032-68-2
• 化学式: C₅₂H₇₉Cl₂N₃O₂Pd
• 分子量: 955.544
• InChiKey: PQUJWVACKSGGNC-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  二(氰基苯)二氯化钯 、 2-[3,5-bis(4-hexadecyloxyphenyl)pyrazol-1-yl]pyridine 以 二氯甲烷 为溶剂， 以74%的产率得到cis-[3,5-bis(4-n-hexadecyloxyphenyl)-1-(pyridin-2-yl)-1H-pyrazole]PdCl2
  参考文献：
  名称：

  Pyridylpyrazole derivatives. A new type of mesogenic bidentate ligands inducing mesomorphism on their related PdX2 complexes

  摘要：

  A new family of 3,5-bis(4-n-alkyloxyphenyl)-1-(pyridin-2-yl)-IH-pyrazole ligands (pypz(R2)) and their complexes of formula c-[PdCl2 (pypz(R2))] have been synthesised and their mesomorphism was investigated. The effectiveness of the asymmetric molecular design in promoting thermotropic mesophases is greater for complexes than for the related ligands, although the latter exhibit mesophases at lower temperatures. These complexes are the first example of metallomesogens containing N,N'-bidentate ligands coordinated to PdCl2. (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s1387-7003(03)00053-4