9′-(pyridin-3-yl)-9′H-9,3′:6′,9″-tercarbazole | 1381953-78-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 9′-(pyridin-3-yl)-9′H-9,3′:6′,9″-tercarbazole
• 英文别名: 3-[3,6-di(9H-carbazol-9-yl)-9H-carbazol-9-yl]pyridine；3-[3,6-di(carbazol-9-yl)carbazol-9-yl]pyridine；3,6-Di(carbazol-9-yl)-9-pyridin-3-ylcarbazole
• CAS: 1381953-78-1
• 化学式: C₄₁H₂₆N₄
• 分子量: 574.684
• InChiKey: VAMZXYKICWPETK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.1
• 重原子数：
  45
• 可旋转键数：
  3
• 环数：
  10.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  27.7
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  3-溴吡啶 在 N-溴代丁二酰亚胺(NBS) 、 铜 、 potassium carbonate 作用下， 以 硝基苯 、 N,N-二甲基甲酰胺 为溶剂， 反应 24.0h， 生成 9′-(pyridin-3-yl)-9′H-9,3′:6′,9″-tercarbazole
  参考文献：
  名称：

  共沉积的三层黄色和白色有机发光二极管的Cu（I）配合物

  摘要：

  四种化合物4- [3,6-二（咔唑-9-基）咔唑-9-基]异喹啉（TCIQ），3- [3,6-二（咔唑-9-基）咔唑-9-基]吡啶设计并合成了含有吡啶基或异喹啉基的（TCPy），4-（咔唑-9-基）异喹啉（4CIQ）和3-（咔唑-9-基）吡啶（CPy）与碘化铜（CuI）共沉积形成原位发光的Cu（I）复合掺杂薄膜，可用作有机发光二极管（OLED）的发光层。发现通过将CuI和TCIQ与调整率共同沉积，可以实现简单的三层黄色和白色OLED。化合物TCIQ既起着形成发光Cu（I）配合物的配体的作用，又起着在黄色OLED中形成的发射体的基质的双重作用，并在白色OLED中起着蓝色发射体的作用。

  DOI：

  10.1002/adfm.201400685

文献信息

• Carbazole compound, light-emitting element, light-emitting device, electronic device, and lighting device
  申请人：Osaka Harue

  公开号：US09029558B2

  公开（公告）日：2015-05-12

  A novel carbazole compound is provided which can be used as a host material for a light-emitting substance (substance emitting fluorescence or substance emitting phosphorescence). A light-emitting element with high emission efficiency, and a light-emitting device, an electronic device, or a lighting device which has low power consumption are provided. A carbazole compound represented by General Formula (G1) below. (In the formula, Ar1 represents any of hydrogen, a substituted or unsubstituted phenyl group, and a carbazolyl group; R1 to R3 each independently represent any of hydrogen, a substituted or unsubstituted phenyl group, and a substituted or unsubstituted biphenyl group; α represents any of a substituted or unsubstituted phenylene group and a substituted or unsubstituted biphenylene group; and n is any of 0, 1, and 2.)

  提供一种新型的咔唑化合物，可用作发光物质（发射荧光或磷光的物质）的宿主材料。提供了具有高发射效率的发光元件，以及具有低功耗的发光器件、电子器件或照明器件。咔唑化合物由下面的一般式（G1）表示。（在公式中，Ar1代表氢、取代或未取代苯基和咔唑基中的任意一种；R1至R3各自独立地代表氢、取代或未取代苯基和取代或未取代联苯基中的任意一种；α代表取代或未取代苯基和取代或未取代联苯基中的任意一种；n为0、1或2中的任意一种。）
• CARBAZOLE COMPOUND, LIGHT-EMITTING ELEMENT, LIGHT-EMITTING DEVICE, ELECTRONIC DEVICE, AND LIGHTING DEVICE
  申请人：Osaka Harue

  公开号：US20130204003A1

  公开（公告）日：2013-08-08

  A novel carbazole compound is provided which can be used as a host material for a light-emitting substance (substance emitting fluorescence or substance emitting phosphorescence). A light-emitting element with high emission efficiency, and a light-emitting device, an electronic device, or a lighting device which has low power consumption are provided. A carbazole compound represented by General Formula (G1) below. (In the formula, Ar 1 represents any of hydrogen, a substituted or unsubstituted phenyl group, and a carbazolyl group; R 1 to R 3 each independently represent any of hydrogen, a substituted or unsubstituted phenyl group, and a substituted or unsubstituted biphenyl group; a represents any of a substituted or unsubstituted phenylene group and a substituted or unsubstituted biphenylene group; and n is any of 0, 1, and 2.)

  提供了一种新的咔唑化合物，可用作发光物质（发射荧光或发射磷光的物质）的主体材料。提供了一种具有高发射效率的发光元件，以及具有低功耗的发光装置、电子装置或照明装置。咔唑化合物由下式（G1）表示。（在公式中，Ar1代表氢、取代或未取代苯基和咔唑基中的任何一种；R1至R3各自独立地代表氢、取代或未取代苯基和取代或未取代联苯基中的任何一种；a代表取代或未取代苯撑基和取代或未取代联苯撑基中的任何一种；n为0、1和2中的任何一种。）
• CARBAZOLE COMPUND LIGHT-EMITTING ELEMENT, LIGHT-EMITTING DEVICE, ELECTRONIC DEVICE, AND LIGHTING DEVICE
  申请人：SEMICONDUCTOR ENERGY LABORATORY CO., LTD.

  公开号：US20150318491A1

  公开（公告）日：2015-11-05

  A novel carbazole compound is provided which can be used as a host material for a light-emitting substance (substance emitting fluorescence or substance emitting phosphorescence). A light-emitting element with high emission efficiency, and a light-emitting device, an electronic device, or a lighting device which has low power consumption are provided. A carbazole compound represented by General Formula (G1) below. (In the formula, Ar 1 represents any of hydrogen, a substituted or unsubstituted phenyl group, and a carbazolyl group; R 1 to R 3 each independently represent any of hydrogen, a substituted or unsubstituted phenyl group, and a substituted or unsubstituted biphenyl group; α represents any of a substituted or unsubstituted phenylene group and a substituted or unsubstituted biphenylene group; and n is any of 0, 1, and 2.)

  提供了一种新型的咔唑化合物，可用作发光物质（发射荧光或发射磷光的物质）的宿主材料。提供了一种具有高发射效率的发光元件，以及具有低功耗的发光装置、电子装置或照明装置。 咔唑化合物由下面的通式（G1）表示。（在公式中，Ar1代表氢、取代或未取代的苯基团和咔唑基团中的任意一种；R1到R3各自独立地代表氢、取代或未取代的苯基团和取代或未取代的联苯基团中的任意一种；α代表取代或未取代的苯撑基团和取代或未取代的联苯撑基团中的任意一种；n是0、1和2中的任意一种。）
• 9-(Pyridin-3-yl)-9H-carbazole derivatives as host materials for green phosphorescent organic light-emitting diodes
  作者：Min Su Park、Jun Yeob Lee

  DOI：10.1016/j.orgel.2013.02.036

  日期：2013.5

  9-(Pyridin-3-yl)-9H-carbazole (PyCz) derivatives were synthesized as bipolar host materials for green phosphorescent organic light-emitting diodes (PHOLEDs) and the device performance was investigated. The PyCz core was modified with carbazole and diphenylamine to prepare the bipolar host materials. Bipolar charge transport properties were observed in the PyCz derivative with the carbazole unit and a high quantum efficiency of 21.3% was obtained in green PHOLEDs. (C) 2013 Elsevier B. V. All rights reserved.
• US9029558B2
  申请人：——

  公开号：US9029558B2

  公开（公告）日：2015-05-12