3,6-di-tert-butyl-9-(p-tolyl)-9H-carbazole | 1394038-61-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 3,6-di-tert-butyl-9-(p-tolyl)-9H-carbazole
• 英文别名: 3,6-Ditert-butyl-9-(4-methylphenyl)carbazole
• CAS: 1394038-61-9
• 化学式: C₂₇H₃₁N
• 分子量: 369.55
• InChiKey: DTLNGMSRYUJOFM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.7
• 重原子数：
  28
• 可旋转键数：
  3
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  4.9
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  4-碘甲苯 、 3,6-二叔丁基咔唑 在 copper(I) oxide 、 2,2,6,6-四甲基-3,5-庚二酮 、 potassium hydroxide 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 24.0h， 以80%的产率得到3,6-di-tert-butyl-9-(p-tolyl)-9H-carbazole
  参考文献：
  名称：

  Copper/β-diketone-catalysed N-arylation of carbazoles

  摘要：

  使用铜/β-二酮催化剂对碳酰胺与芳基碘化物进行N-芳基化反应，具有广泛的底物适用性和中等至良好的产率。

  DOI：

  10.1039/c5ra07690k

文献信息

• [EN] POLYCYCLIC COMPOUNDS FOR ELECTRONIC APPLICATIONS<br/>[FR] COMPOSÉS POLYCYCLIQUES POUR DES APPLICATIONS ÉLECTRONIQUES
  申请人：BASF SE

  公开号：WO2010046259A1

  公开（公告）日：2010-04-29

  The present invention relates to electronic devices, especially electroluminescent devices, comprising compounds of formula (I), and/or (II), especially as host for phosphorescent emitters, electron transporting materials, or emitter materials. The hosts may function with phosphorescent materials to provide improved efficiency, stability, manufacturability, or spectral characteristics of electroluminescent devices.

  本发明涉及电子设备，特别是包含化合物(I)和/或(II)的电致发光器件，特别是作为磷光发射体、电子传输材料或发射材料的宿主。这些宿主可以与磷光材料配合使用，以提高电致发光器件的效率、稳定性、可制造性或光谱特性。
• Electrochemical and Spectral Characterizations of 9-Phenylcarbazoles
  作者：Ssu-Kai Chiu、Yi-Chun Chung、Guey-Sheng Liou、Yuhlong Oliver Su

  DOI：10.1002/jccs.201100601

  日期：2012.3

  electrochemical as well as spectral properties. For 3,6‐substituted carbazoles, the oxidation is reversible and the potential is affected by the substituents. For 3,6‐unprotected carbazoles, on the other hand, the oxidized forms can undergo dimerization. Their corresponding dimers have been independently synthesized by chemical methods and have exhibited identical spectral properties. The para position of

  已合成了一系列9-苯基咔唑，并对其电化学和光谱性质进行了表征。对于3,6-取代的咔唑，氧化是可逆的，并且电势受取代基影响。另一方面，对于3,6-未保护的咔唑，其氧化形式可能会发生二聚化。它们相应的二聚体已通过化学方法独立合成，并显示出相同的光谱特性。在对9-苯基的位置对于氧化还原反应和化学反应相对地不敏感。与它们的三苯胺对应物相比，氨基衍生物的咔唑阳离子自由基形式不稳定。
• [EN] METAL COMPLEXES WITH DIBENZO[F,H]QUINOXALINES<br/>[FR] COMPLEXES MÉTALLIQUES COMPRENANT DES DIBENZO[F,H]QUINOXALINES
  申请人：BASF SE

  公开号：WO2013104649A1

  公开（公告）日：2013-07-18

  This invention relates to electroluminescent metal complexes of the formula electronic devices comprising the metal complexes and their use in electronic devices, especially organic light emitting diodes (OLEDs). The metal complexes of formula (I) show high emission efficiency, excellent vaporizability, thermal stability, processing stability, high charge carrier mobilities, low turn-on voltage and high temperature stability of the emission color.

  该发明涉及公式为电致发光金属配合物的电子器件，包括金属配合物及其在电子器件中的应用，特别是有机发光二极管（OLEDs）。公式（I）的金属配合物显示出高发射效率、优异的蒸发性、热稳定性、加工稳定性、高载流子迁移率、低开启电压和发射颜色的高温稳定性。
• PYRROLOPYRROLE DERIVATIVES, THEIR MANUFACTURE AND USE AS SEMICONDUCTORS
  申请人：Hayoz Pascal

  公开号：US20120095236A1

  公开（公告）日：2012-04-19

  The present invention relates to compounds of the formula (I) wherein the substituents are as defined in claim 1 , and their use as organic semiconductor in organic devices, like diodes, organic field effect transistors and/or solar cells. The compounds of the formula I have excellent solubility in organic solvents. High efficiency of energy conversion, excellent field-effect mobility, good on/off current ratios and/or excellent stability can be observed, when said compounds are used in semiconductor devices or organic photovoltaic (PV) devices (solar cells).

  本发明涉及式(I)中所述取代基的化合物，其中所述取代基如权利要求1所定义，并且它们作为有机半导体在有机器件中的使用，例如二极管、有机场效应晶体管和/或太阳能电池。式I的化合物具有优异的有机溶剂溶解性。当所述化合物用于半导体器件或有机光伏（PV）器件（太阳能电池）时，可以观察到高效能转换率、优异的场效应迁移率、良好的开关电流比和/或优异的稳定性。
• ORGANIC ELECTROLUMINESCENT DEVICE AND METHOD FOR MANUFACTURE THEREOF
  申请人：Beijing Visionox Technology Co., Ltd.

  公开号：EP3070757A1

  公开（公告）日：2016-09-21

  The present invention discloses an organic electroluminescent device and a manufacturing method thereof. The host material of the light-emitting layer of the organic electroluminescent device is material in which the triplet state energy level of the CT excited state is higher than that of the n-π excited state by 0 to 0.3 eV; or the triplet state of the host material of the light-emitting layer is higher than that of the n-π excited state by more than 1.0 eV; in addition, the difference in energy level between the second triplet state of the n-π state and the first singlet state of the CT excited state is -0.1 to 0.1 eV; and the luminescent dye is a fluorescent dye. With regard to the organic electroluminescent device in the present invention, as new host material in the light-emitting layer is used and the host material has a donor group and an acceptor group, the triplet state in the light-emitting layer may be fully utilized to achieve a 100% light-emitting efficiency in the fluorescent device. Furthermore, no noble metal is required to be used, thus reducing the cost.

  本发明公开了一种有机电致发光器件及其制造方法。有机电致发光器件的发光层的主材料是 CT 激发态的三重态能级比 n-π 激发态的三重态能级高 0 至 0.3 eV；或发光层主材料的三重态比n-π激发态的三重态高1.0 eV以上；此外，n-π态的第二三重态与CT激发态的第一单重态之间的能级差为-0.1至0.1 eV；且发光染料为荧光染料。就本发明的有机电致发光器件而言，由于在发光层中使用了新的宿主材料，且宿主材料具有供体基团和受体基团，因此可以充分利用发光层中的三重态，使荧光器件的发光效率达到 100%。此外，无需使用贵金属，从而降低了成本。