| 173976-44-8

• CAS: 173976-44-8
• 化学式: C₂₅H₂₆ClFeOPSn
• 分子量: 583.465
• InChiKey: PTDUSAIONYOKPL-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  盐酸 、 以 甲醇 、 乙醚 为溶剂， 以70%的产率得到
  参考文献：
  名称：

  Synthesis and structural studies of 2-stannyl-substituted ferrocenylmethylamine and -phosphine derivatives 2-Me2RSnFcCH2Y (RMe, Cl; YNMe2, PPh2, P(O)Ph2; FcC10H8Fe)

  摘要：

  2-(Trimethylstannyl)ferrocenylmethyldiphenylphosphine, 2-Me(3)SnFcCH(2)PPh(2) (2a), was synthesized from 2-Me(3)SnFcCH(2)NMe(2) (1a) and Ph(2)PH. Compound 2a is oxidized with H2O2 to 2-Me(3)SnFcCH(2)P(O)Ph(2) (3a). Halogenation of la and 2a with Me(2)SnCl(2) and 3a with HCl-diethyl ether yields the organotin monochlorides 2-Me(2)(Cl)SnFcCH(2)Y (1b, Y = NMe(2); 2b, Y = PPh(2); 3b, Y = P(O)Ph(2)). Both crystal structure determinations and multinuclear magnetic resonance studies in solution reveal for 1b-3b molecular structures in which the tin atom approaches a trigonal bipyramidal pentacoordination as a consequence of an intramolecular Y Sn interaction. The donor strength of Y increases in the order PPh(2) < NMe(2) < P(O)Ph(2). In solution 1b and 2b undergo ligand-exchange processes.

  DOI：

  10.1016/0022-328x(95)05549-5