cyclohex-3-enyl 2,3-epoxypropyl ether | 1287297-51-1

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: cyclohex-3-enyl 2,3-epoxypropyl ether
• 英文别名: 2-(Cyclohex-3-en-1-yloxymethyl)oxirane
• CAS: 1287297-51-1
• 化学式: C₉H₁₄O₂
• 分子量: 154.209
• InChiKey: GFYKTXPOLUFWRD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.3
• 重原子数：
  11
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.78
• 拓扑面积：
  21.8
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  endo-5-aminomethylbicyclo[2.2.1]hept-2-ene 、 cyclohex-3-enyl 2,3-epoxypropyl ether 以 异丙醇 为溶剂， 以53%的产率得到1-(bicyclo[2.2.1]hept-5-en-endo-2-ylmethylamino)-3-(cyclohex-3-en-1-yloxy)propan-2-ol
  参考文献：
  名称：

  Experimental and theoretical study on the reaction of bicyclo[2.2.1]hept-5-en-endo-2-ylmethanamine with glycidyl ethers

  摘要：

  Reactions of bicyclo[2.2.1]hept-5-en-endo-2-ylmethanamine with phenyl, 4-methylphenyl, 3-methylphenyl, 2-methylphenyl, 4-methoxyphenyl, cyclohexyl, and cyclohexenyl 2,3-epoxypropyl ethers gave the corresponding N-mono- and N,N-bis(3-R-oxy-2-hydroxypropyl) derivatives. The structure of the newly synthesized amino alcohols and regioselectivity of oxirane ring opening were determined by IR spectroscopy, H-1 and C-13 NMR, and mass spectrometry. The reaction mechanism was studied by quantum chemistry at the PCM/B3LYP/6-31G(d) level of theory.

  DOI：

  10.1134/s1070428011010088

文献信息

• Composites and epoxy resins based on aryl substituted compounds
  申请人：Hexion Inc.

  公开号：US10040914B2

  公开（公告）日：2018-08-07

  Compositions and methods for forming epoxy resin are provided, and compositions and methods for forming epoxy resin composites are provided. In one embodiment, a composite comprises an epoxy resin composition comprising an epoxy resin component comprising a glycidyl ether of an aryl substituted phenolic compound, a curing agent component, and a substrate. In one embodiment, a composite comprises an epoxy resin composition comprising an epoxy resin component and a curing agent component comprising an aryl substituted phenolic compound, and a substrate.

  提供了用于形成环氧树脂的组合物和方法，以及用于形成环氧树脂复合材料的组合物和方法。在一个实施方案中，复合材料包括环氧树脂组合物，其中环氧树脂组合物包括芳基取代酚类化合物的缩水甘油醚、固化剂组合物和基底。在一个实施例中，一种复合材料包括一种环氧树脂组合物，该组合物包含一种环氧树脂组分和一种固化剂组分，该固化剂组分包含一种芳基取代的酚类化合物和一种基材。
• Thermally stable, low birefringent copolyimide films
  申请人：Sun Limin

  公开号：US11084906B2

  公开（公告）日：2021-08-10

  A class of solvent resistant, flexible copolyimide substrates having high optical transparency (>80% from 400 to 750 nm) that is retained after brief exposure to 300° C., near-zero birefringence (<0.001) and a maximum CTE of approximately 60 ppm/° C. is disclosed. The copolyimides are prepared from alicyclic dianhydrides, aromatic cardo diamines, and aromatic diamines containing free carboxyl groups. The substrates are manufactured from solutions of the copolyimides containing multifunctional epoxides in the form of single layer films, multilayer laminates and glass fiber reinforced composite films. The substrates can be used in the construction of flexible optical displays, and other microelectronic and photovoltaic devices that require their unique combination of properties.

  本发明公开了一类耐溶剂、柔性共聚亚胺基材，其光学透明度高（从 400 纳米到 750 纳米>80%），在短暂暴露于 300° C 后仍能保持，双折射近乎零（<0.001），最大 CTE 约为 60 ppm/°C。共聚亚胺是由脂环族二酐、芳香族辛二胺和含有游离羧基的芳香族二胺制备而成。基材由含有多功能环氧化物的共聚亚胺溶液制成，其形式包括单层膜、多层复合膜和玻璃纤维增强复合膜。这些基材可用于制造柔性光学显示器以及其他需要其独特组合特性的微电子和光伏设备。
• Epoxy resin composition, prepreg, and fiber-reinforced composite material
  申请人：Toray Industries, Inc.

  公开号：US11345808B2

  公开（公告）日：2022-05-31

  The present invention aims to provide an epoxy resin composition that is high in both fast curability and storage stability, a prepreg prepared by using the epoxy resin composition, and a fiber reinforced composite material prepared by curing the prepreg. The epoxy resin composition contains the following components [A], [B], [C], and [D] and meets the following requirements [a], [b], and [c]: [A]: epoxy resin, [B]: dicyandiamide, [C]: aromatic urea, [D]: borate ester, [a]: 0.014≤(content of component [D]/content of component [C])≤0.045, [b]: 0.9≤(number of moles of active groups in component [A]/number of moles of active hydrogen in component [B])≤1.2, and [c]: 14≤(content of component [A]/content of component [C])≤25.

  本发明旨在提供一种快速固化性和储存稳定性都很高的环氧树脂组合物、一种使用该环氧树脂组合物制备的预浸料，以及一种通过固化该预浸料制备的纤维增强复合材料。 环氧树脂组合物包含以下组分[A]、[B]、[C]和[D]，并满足以下要求[a]、[b]和[c]： [A]：环氧树脂、 [B]：双氰胺、 [C]：芳香族脲 [D]：硼酸酯、 [a]:0.014≤（组分[D]含量/组分[C]含量）≤0.045、 [b]:0.9≤（组分[A]中活性基团的摩尔数/组分[B]中活性氢的摩尔数）≤1.2，以及 [c]:14≤（组分[A]的含量/组分[C]的含量）≤25。
• COMPOSITES AND EPOXY RESINS BASED ON ARYL SUBSTITUTED COMPOUNDS
  申请人：Hexion Inc.

  公开号：US20170051119A1

  公开（公告）日：2017-02-23

  Compositions and methods for forming epoxy resin are provided, and compositions and methods for forming epoxy resin composites are provided. In one embodiment, a composite comprises an epoxy resin composition comprising an epoxy resin component comprising a glycidyl ether of an aryl substituted phenolic compound, a curing agent component, and a substrate. In one embodiment, a composite comprises an epoxy resin composition comprising an epoxy resin component and a curing agent component comprising an aryl substituted phenolic compound, and a substrate.
• EPOXY RESIN COMPOSITION, PREPREG, AND FIBER-REINFORCED COMPOSITE MATERIAL
  申请人：Toray Industries, Inc.

  公开号：US20200140676A1

  公开（公告）日：2020-05-07

  The present invention aims to provide an epoxy resin composition that is high in both fast curability and storage stability, a prepreg prepared by using the epoxy resin composition, and a fiber reinforced composite material prepared by curing the prepreg. The epoxy resin composition contains the following components [A], [B], [C], and [D] and meets the following requirements [a], [b], and [c]: [A]: epoxy resin, [B]: dicyandiamide, [C]: aromatic urea, [D]: borate ester, [a]: 0.014≤(content of component [D]/content of component [C])≤0.045, [b]: 0.9≤(number of moles of active groups in component [A]/number of moles of active hydrogen in component [B])≤1.2, and [c]: 14≤(content of component [A]/content of component [C])≤25.