[Ni(2,3-dimethyl-4-formyl(benzhydrazide)-1-phenyl-3-pyrazolin-5-one)Br2] | 756492-57-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: [Ni(2,3-dimethyl-4-formyl(benzhydrazide)-1-phenyl-3-pyrazolin-5-one)Br2]
• 英文别名: dibromonickel;N-[(E)-(1,5-dimethyl-3-oxo-2-phenylpyrazol-4-yl)methylideneamino]benzamide
• CAS: 756492-57-6
• 化学式: C₃₈H₃₆Br₂N₈NiO₄
• 分子量: 887.253
• InChiKey: GYMOSIPYOKQRKN-APYLNELOSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  nickel(II) bromide trihydrate 、 1,2-dihydro-1,5-dimethyl-2-phenyl-4-formyl(benzhydrazide)-3H-pyrazol-3-one 以 丙酮 为溶剂， 以86%的产率得到[Ni(2,3-dimethyl-4-formyl(benzhydrazide)-1-phenyl-3-pyrazolin-5-one)Br2]
  参考文献：
  名称：

  Complexes of Nickel(II) with 2,3‐Dimethyl‐4‐formyl(benzhydrazide)‐1‐phenyl‐3‐pyrazolin‐5‐one

  摘要：

  Nickel(II) complexes of the Schiff base 2,3-dimethyl-4-formyl-(benzhydrazide)-1-phenyl-3-pyrazolin-5-one (L) with the formulae [Ni(L)(2) (ClO4)]ClO4, [Ni(L)(2)(NO3)](NO3), and [Ni(L)(2)X-2] (X = Cl, Br, or I) have been synthesized and characterized by elemental analyses, electrical conductance in nonaqueous solvents, infrared and electronic spectra as well as magnetic susceptibility measurements. In these complexes, L acts as a neutral bidentate ligand coordinating through the azomethine nitrogen and the carbonyl oxygen of the pyrazolone ring. In the perchlorate and nitrate complexes one of the anions is coordinated to the metal ion in a bidentate fashion while in the halide complexes both the anions are coordinated. An octahedral geometry is assigned around the nickel(II) ion in all these complexes.

  DOI：

  10.1081/sim-120030430