N-(triphenylenemethyl)propylamine | 166898-52-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: N-(triphenylenemethyl)propylamine
• CAS: 166898-52-8
• 化学式: C₂₂H₂₁N
• 分子量: 299.415
• InChiKey: FIWZXRKQLYQVRI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.65
• 重原子数：
  23.0
• 可旋转键数：
  4.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  12.03
• 氢给体数：
  1.0
• 氢受体数：
  1.0

反应信息

• 作为反应物：
  描述：

  N-(triphenylenemethyl)propylamine 在 potassium carbonate 、 三乙胺 作用下， 以 甲醇 、 二氯甲烷 为溶剂， 反应 0.33h， 生成 <<1⁵,3⁵,5⁵,7⁵-tetra-tert-butyl-7²-<carbamoyl>methoxy>-1,3,5,7-tetrabenzocyclooctophane-1²,3²,5²-triyl>trioxy>triacetic acid
  参考文献：
  名称：

  New Sensitizer-Modified Calix[4]arenes Enabling Near-UV Excitation of Complexed Luminescent Lanthanide Ions

  摘要：

  The synthesis is described of a series of calix[4]arenes with three different sensitizer chromophores (''antenna'') attached to the lower rim via a short spacer. In the Eu3+ and Tb3+ complexes of these calixarenes, photoexcitation of the antenna can induce lanthanide emission via intramolecular energy transfer. Although the higher energy of the Tb3+ luminescent state makes it more difficult to sensitize than in the case of Eu3+, especially a triphenylene antenna is found to have strong sensitizing ability toward not only Eu3+ but also Tb3+, allowing excitation of the lanthanide with wavelengths extending to 350 nm.

  DOI：

  10.1021/ja00142a004
• 作为产物：
  描述：

  9,10-苯并菲 在 四氯化钛 、 sodium cyanoborohydride 、 溶剂黄146 作用下， 以 二氯甲烷 为溶剂， 反应 4.0h， 生成 N-(triphenylenemethyl)propylamine
  参考文献：
  名称：

  New Sensitizer-Modified Calix[4]arenes Enabling Near-UV Excitation of Complexed Luminescent Lanthanide Ions

  摘要：

  The synthesis is described of a series of calix[4]arenes with three different sensitizer chromophores (''antenna'') attached to the lower rim via a short spacer. In the Eu3+ and Tb3+ complexes of these calixarenes, photoexcitation of the antenna can induce lanthanide emission via intramolecular energy transfer. Although the higher energy of the Tb3+ luminescent state makes it more difficult to sensitize than in the case of Eu3+, especially a triphenylene antenna is found to have strong sensitizing ability toward not only Eu3+ but also Tb3+, allowing excitation of the lanthanide with wavelengths extending to 350 nm.

  DOI：

  10.1021/ja00142a004