4-(4-(3,3,4,4,5,5-hexafluoro-2-(2-methyl-5-phenylthiophen-3-yl)cyclopent-1-enyl)-5-methylthiophen-2-yl)aniline | 1263304-47-7

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: 4-(4-(3,3,4,4,5,5-hexafluoro-2-(2-methyl-5-phenylthiophen-3-yl)cyclopent-1-enyl)-5-methylthiophen-2-yl)aniline
• CAS: 1263304-47-7
• 化学式: C₂₇H₁₉F₆NS₂
• 分子量: 535.577
• InChiKey: VKZQTSPVTHBZBA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.17
• 重原子数：
  36.0
• 可旋转键数：
  4.0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.19
• 拓扑面积：
  26.02
• 氢给体数：
  1.0
• 氢受体数：
  3.0

反应信息

• 作为反应物：
  描述：

  4-(4-(3,3,4,4,5,5-hexafluoro-2-(2-methyl-5-phenylthiophen-3-yl)cyclopent-1-enyl)-5-methylthiophen-2-yl)aniline 生成
  参考文献：
  名称：

  Fluorescent Quenching of Lanthanide-Doped Upconverting Nanoparticles by Photoresponsive Polymer Shells

  摘要：

  A photoresponsive amphiphilic polymer was synthesized and used to encapsulate upconverting lanthanide-doped nanoparticles to produce a novel water-dispersible nanoassembly with a high loading of emission quenchers. The nanoassembly exhibits fluorescent emission in the visible region upon irradiation with 980 nm light, which can be reversibly modulated by toggling the isomeric state of photoresponsive chromophores attached to the polymer's backbone using UV and visible light. Photon counting experiments show that the quenching mechanism for this new nanoassembly is a combination of Forster resonance energy transfer (FRET) and emission-reabsorption. Compared to the similar nanoassembly prepared from a reported "plug-and-play" method, this new nanoassembly has higher overall quenching efficiency due to the increased photoswitch loading (14 times compared to the

  DOI：

  10.1021/cm5021405
• 作为产物：
  描述：

  3,5-二溴-2-甲基噻吩 在 N-溴代丁二酰亚胺(NBS) 、 四(三苯基膦)钯 、 正丁基锂 、 sodium carbonate 作用下， 以 四氢呋喃 、 正己烷 、 水 、 甲苯 为溶剂， 反应 61.0h， 生成 4-(4-(3,3,4,4,5,5-hexafluoro-2-(2-methyl-5-phenylthiophen-3-yl)cyclopent-1-enyl)-5-methylthiophen-2-yl)aniline
  参考文献：
  名称：

  电子对光开关二噻吩乙烯-硫脲有机催化剂动态范围的影响

  摘要：

  制备了带有光开关二噻吩乙烯 (DTE) 核和各种取代基的硫脲基有机催化剂，并广泛测试了它们加速乙酰丙酮和反式-β-硝基苯乙烯之间迈克尔反应的能力。调节基团的 Hammett 参数与紫外线照射后的催化活性之间存在很强的相关性。吸电子基团在开环形式和闭环异构体的催化剂之间提供最大的反应性差异，有证据表明在 oDTE 和 cDTE 中两半之间存在电子耦合。

  DOI：

  10.1021/acs.joc.2c02987

文献信息

• Multifunctional photo- and thermo-responsive copolymer nanoparticles
  作者：Seon-Jeong Lim、Carl-Johan Carling、C. Chad Warford、Dennis Hsiao、Byron D. Gates、Neil R. Branda

  DOI：10.1016/j.dyepig.2010.03.013

  日期：2011.6

  A novel amphiphilic photochromic copolymer P1-o consisting of a hydrophilic poly(N-isopropylacrylamide) backbone and thermally irreversible photochromic and hydrophobic 1,2-dithienylethene derivative pendants was designed, synthesized and used to fabricate self-assembled copolymer nanoparticles in an aqueous condition. The hydrodynamic diameters of the multifunctional copolymer P1-o nanoparticles reversibly switched between two stable states with two stimuli: light and temperature in an aqueous suspension.Graphical abstract:(C) 2010 Elsevier Ltd. All rights reserved.
• Highly-stable red-emissive photochromic nanoparticles based on a diarylethene-perylenebisimide dyad
  作者：Issei Ikariko、Sei Deguchi、Nicolas Fabre、Sanae Ishida、Sunnam Kim、Seiji Kurihara、Rémi Métivier、Tuyoshi Fukaminato

  DOI：10.1016/j.dyepig.2020.108490

  日期：2020.9

  Design and synthesis of highly-stable red-emissive photochromic nanoparticles (NPs) are essential tasks for the development of next-generation microscopic technologies. In this scope, we have prepared red-emissive photochromic NPs based on a diarylethene-perylenebisimide (DAE-PBI) dyad. In order to achieve both high fluorescence and outstanding photostability in the NP state, the fluorescence properties of PBI fluorophores having bulky substituents at the bay-positions were investigated in solution as well as in the NP state. The prepared DAE-PBI dyad shows bright red emission, complete ON-OFF contrast with nonlinear photoswitching response, and excellent photostability in the NP state. In addition, the fluorescence photoswitching property and the photostability at the single NP level was investigated under fluorescence microscope.