2,6-di(9H-3,9'-bicarbazol-9-yl)pyridine | 1611484-34-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 2,6-di(9H-3,9'-bicarbazol-9-yl)pyridine
• 英文别名: 3-Carbazol-9-yl-9-[6-(3-carbazol-9-ylcarbazol-9-yl)pyridin-2-yl]carbazole
• CAS: 1611484-34-4
• 化学式: C₅₃H₃₃N₅
• 分子量: 739.879
• InChiKey: MBKRMJNKZAGZFS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  13.8
• 重原子数：
  58
• 可旋转键数：
  4
• 环数：
  13.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  32.6
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  咔唑 在 potassium iodate 、 铜 、 potassium carbonate 、 potassium iodide 、 potassium hydroxide 作用下， 以 溶剂黄146 、 N,N-二甲基甲酰胺 为溶剂， 反应 132.0h， 生成 2,6-di(9H-3,9'-bicarbazol-9-yl)pyridine
  参考文献：
  名称：

  新型含吡啶环咔唑衍生物的合成及光学性质

  摘要：

  通过简单的程序，通过碘反应和乌尔曼反应，合成了一系列具有吡啶核和咔唑臂的新型单分散，定义明确的分子。通过IR，1 H NMR，13 C NMR和元素分析确认了它们的结构。此外，荧光光谱表明这些化合物表现出强荧光，最大波长在373至385nm范围内。

  DOI：

  10.1002/jhet.1639

文献信息

• Mixture, composition and organic electronic device
  申请人：GUANGZHOU CHINARAY OPTOELECTRONIC MATERIALS LTD.

  公开号：US10978642B2

  公开（公告）日：2021-04-13

  A mixture consists of three or more organic compounds, wherein the molecular weight difference of any two organic compounds is less than 160 Dalton. In the mixture, the molar percentage of each organic compound is not less than 3% and not more than 90%, and the organic compounds all have at least one same or similar photoelectronic function.

  混合物由三种或三种以上的有机化合物组成，其中任意两种有机化合物的分子量之差小于 160 道尔顿。在混合物中，每种有机化合物的摩尔百分比不小于 3%，也不大于 90%，并且所有有机化合物都具有至少一种相同或相似的光电子功能。
• ORGANIC MIXTURE, ORGANIC COMPOSITION, ORGANIC ELECTRONIC COMPONENT AND PREPARATION METHOD THEREFOR
  申请人：GUANGZHOU CHINARAY OPTOELECTRONIC MATERIALS LTD.

  公开号：US20190355911A1

  公开（公告）日：2019-11-21

  An organic mixture, an organic composition, an organic electronic component, and a preparation method therefor. The organic mixture comprises two organic compounds H1 and H2, the organic compound H1 being a spiro compound, the organic compound H1 being a compound comprising rich electrons, min((LUMO(H1)−HOMO(H2)), (LUMO(H2)−HOMO(H1)))≤min (ET(H1), ET(H2))+0.1 eV, the LUMO(H1), HOMO(H1) and ET(H1) respectively indicating a lowest unoccupied molecular orbital, a highest occupied molecular orbital and a triplet-state energy level of the organic compound H1, and the LUMO(H2), HOMO(H2) and ET(H2) respectively indicating a lowest unoccupied molecular orbital, a highest occupied molecular orbital and a triplet-state energy level of the organic compound H2.
• MIXTURE, COMPOSITION AND ORGANIC ELECTRONIC DEVICE
  申请人：GUANGZHOU CHINARAY OPTOELECTRONIC MATERIALS LTD.

  公开号：US20200098992A1

  公开（公告）日：2020-03-26

  A mixture consists of three or more organic compounds, wherein the molecular weight difference of any two organic compounds is less than 160 Dalton. In the mixture, the molar percentage of each organic compound is not less than 3% and not more than 90%, and the organic compounds all have at least one same or similar photoelectronic function.