4-methoxy-3-methylcyclohex-3-ene-1-carbaldehyde | 135885-54-0

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 4-methoxy-3-methylcyclohex-3-ene-1-carbaldehyde
• CAS: 135885-54-0
• 化学式: C₉H₁₄O₂
• 分子量: 154.209
• InChiKey: WYSLMRFFZRZKNK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.91
• 重原子数：
  11.0
• 可旋转键数：
  2.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  26.3
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  p-bromobenzenesulfonyl azide 、 4-methoxy-3-methylcyclohex-3-ene-1-carbaldehyde 反应 10.0h， 以63%的产率得到4-Bromo-N-[1-(3-formyl-1-methyl-cyclopentyl)-1-methoxy-meth-(Z)-ylidene]-benzenesulfonamide
  参考文献：
  名称：

  Ultrasonically accelerated cycloaddition - rearrangement of enol ethers

  摘要：

  Cycloaddition-rearrangement reactions of methyl cyclohexenyl ethers with p-bromobenzenesulfonyl azide in neat homogeneous admixture are substanially accelerated by low-wattage ultrasound. Using ultrasound approximately the same yields of rearranged products are obtained in less time at lower temperature than observed at ambient sonic frequencies and elevated temperature. A previously unreported product structural type has also been found.

  DOI：

  10.1016/s0040-4039(00)74352-8