2-(trimethylsilyl)ethyl 2,3,6-tri-O-acetyl-4-O-<2,3,6-tri-O-acetyl-4-O-(3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido-β-D-galactopyranosyl)-β-D-galactopyranosyl>-β-D-glucopyranoside | 117252-82-1

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 2-(trimethylsilyl)ethyl 2,3,6-tri-O-acetyl-4-O-<2,3,6-tri-O-acetyl-4-O-(3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido-β-D-galactopyranosyl)-β-D-galactopyranosyl>-β-D-glucopyranoside
• 英文别名: [(2R,3R,4S,5R,6R)-4,5-diacetyloxy-3-[(2S,3R,4S,5S,6R)-3,4-diacetyloxy-6-(acetyloxymethyl)-5-[(2S,3R,4R,5R,6R)-4,5-diacetyloxy-6-(acetyloxymethyl)-3-(1,3-dioxoisoindol-2-yl)oxan-2-yl]oxyoxan-2-yl]oxy-6-(2-trimethylsilylethoxy)oxan-2-yl]methyl acetate
• CAS: 117252-82-1
• 化学式: C₄₉H₆₅NO₂₆Si
• 分子量: 1112.13
• InChiKey: XNFMYMQPORJFJU-NYEUKSPQSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.23
• 重原子数：
  77
• 可旋转键数：
  30
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.65
• 拓扑面积：
  330
• 氢给体数：
  0
• 氢受体数：
  26

反应信息

• 作为反应物：
  描述：

  2-(trimethylsilyl)ethyl 2,3,6-tri-O-acetyl-4-O-<2,3,6-tri-O-acetyl-4-O-(3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido-β-D-galactopyranosyl)-β-D-galactopyranosyl>-β-D-glucopyranoside 生成 1,2,3,6-tetra-O-acetyl-4-O-<2,3,6-tri-O-acetyl-4-O-(3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido-β-D-galactopyranosyl)-β-D-galactopyranosyl>-β/α-D-glucopyranose
  参考文献：
  名称：

  JANSSON, KARL;AHLFORS, STEFAN;FREJD, TORBJORN;KIHLBERG, JAN;MAGNUSSON, GO+, J. ORG. CHEM., 53,(1988) N 24, C. 5629-5647

  摘要：

  DOI：
• 作为产物：
  描述：

  2-(Trimethylsilyl)ethyl-<2,3,4,6-tetra-O-acetyl-α-D-mannopyranosid> 生成 2-(trimethylsilyl)ethyl 2,3,6-tri-O-acetyl-4-O-<2,3,6-tri-O-acetyl-4-O-(3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido-β-D-galactopyranosyl)-β-D-galactopyranosyl>-β-D-glucopyranoside
  参考文献：
  名称：

  JANSSON, KARL;AHLFORS, STEFAN;FREJD, TORBJORN;KIHLBERG, JAN;MAGNUSSON, GO+, J. ORG. CHEM., 53,(1988) N 24, C. 5629-5647

  摘要：

  DOI：

文献信息

• 2-(Trimethylsilyl)ethyl glycosides. 3. Synthesis, anomeric deblocking, and transformation into 1,2-trans 1-O-acyl sugars
  作者：Karl Jansson、Stefan Ahlfors、Torbjoern Frejd、Jan Kihlberg、Goeran Magnusson、Jan Dahmen、Ghazi Noori、Kristina Stenvall

  DOI：10.1021/jo00259a006

  日期：1988.11