4-环氧乙烷基-1,2-环己烷二醇 | 45895-09-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• 中文名称: 4-环氧乙烷基-1,2-环己烷二醇
• 英文名称: 4-(Oxiran-2-yl)cyclohexane-1,2-diol
• CAS: 45895-09-8
• 化学式: C₈H₁₄O₃
• 分子量: 158.19
• InChiKey: GBMLUULWTGGUAO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.2
• 重原子数：
  11
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  53
• 氢给体数：
  2
• 氢受体数：
  3

文献信息

• DISPERSION COMPOSITION, CURABLE COMPOSITION USING THE SAME, TRANSPARENT FILM, MICROLENS, AND SOLID-STATE IMAGING DEVICE
  申请人：FUJIFILM Corporation

  公开号：EP3124548A1

  公开（公告）日：2017-02-01

  Provided is a dispersion composition which has a high refractive index. The surface of a film coated from the dispersion has an excellent surface condition. Also provided is a curable composition comprising the dispersion, a transparent film, a microlens and a solid-state imaging device. The dispersion composition comprises: colourless, white or transparent metal oxide particles (A) having a primary particle diameter of 1 nm to 100 nm and a refractive index of from 1.75 to 2.70; a polymer compound (B) having an acid value of less than 120 mgKOH/g and being represented by Formula (1); and a solvent (C):         (A1-R2)̵n-R1(̵P1)m     Formula (1) wherein: R1 represents a (m+n)-valent linking group represented by any one of the following Formulae: wherein: L3 represents a trivalent group; T3 represents a single bond or a divalent linking group; and the three T3's may be the same or different; L4 represents a tetravalent group; T4 represents a single bond or a divalent linking group, and the four T4's may be the same or different; L5 represents a pentavalent group; T5 represents a single bond or a divalent linking group, and the five T5's may be the same or different; L6 represents a hexavalent group; T6 represents a single bond or a divalent linking group, and the six T6's may be the same or different; R2 represents a single bond or a divalent linking group, A1 represents a monovalent substituent having at least one group selected from the group consisting of an acid group, a urea group, a urethane group, a group having a coordinating oxygen atom, a group having a basic nitrogen atom, a phenol group, an alkyl group, an aryl group, a group having an alkyleneoxy chain, an imide group, an alkyloxycarbonyl group, an alkyl amino carbonyl group, a carboxylate group, a sulfonamide group, a heterocyclic group, an alkoxysilyl group, an epoxy group, an isocyanate group, and a hydroxyl group, n A1's and n R2's may be the same or different, m represents a positive number of 8 or less, n represents 1 to 9, and m+n satisfies 3 to 10, and P1 represents a polymer chain, and m P1's may be the same or different.

  本文提供了一种具有高折射率的分散组合物。用该分散体涂覆的薄膜表面具有极佳的表面状态。此外，还提供了一种可固化组合物，其中包括该分散液、透明薄膜、微透镜和固态成像装置。 分散体组合物包括 无色、白色或透明的金属氧化物颗粒（A），其主颗粒直径为 1 纳米至 100 纳米，折射率为 1.75 至 2.70； 聚合物化合物（B），其酸值小于 120 mgKOH/g，由式（1）表示；以及 溶剂 (C)： (A1-R2)̵n-R1(̵P1)m 式 (1) 其中 R1 代表由下式中任一个式子表示的 (m+n) 价连接基团： 其中 L3 代表三价基团；T3 代表单键或二价连接基团，三个 T3 可以相同或不同； L4 代表四价基团；T4 代表单键或二价连接基团，四个 T4 可以相同或不同；L5 代表五价基团；T5 代表单键或二价连接基团，五个 T5 可以相同或不同； L6 代表六价基团；T6 代表单键或二价连接基团，六个 T6 可以相同或不同； R2 代表单键或二价连接基团、 A1 代表一个单价取代基，该取代基至少有一个基团选自以下组别：酸基、脲基、氨基甲酸乙酯基、具有配位氧原子的基团、具有碱性氮原子的基团、酚基、烷基、芳基、烷基、醚基、醚基、醚基、醚基、醚基、醚基、醚基、醚基、醚基、醚基、醚基、醚基、酰亚胺基、烷氧基羰基、烷基氨基羰基、羧酸基、磺酰胺基、杂环基、烷氧基硅基、环氧基、异氰酸酯基和羟基、 n 个 A1 和 n 个 R2 可以相同或不同、 m 代表 8 或以下的正数，n 代表 1 至 9，m+n 满足 3 至 10，以及 P1 代表聚合物链，m 个 P1 可以相同或不同。
• DISPERSION COMPOSITION, AND CURABLE COMPOSITION, TRANSPARENT FILM, MICROLENS AND SOLID-STATE IMAGING ELEMENT USING SAME
  申请人：FUJIFILM Corporation

  公开号：EP3135733A1

  公开（公告）日：2017-03-01

  Provided is a dispersion composition which has a high refractive index and has a high dispersion stability, a curable composition using the same, a transparent film, a microlens, and a solid-state imaging device. The dispersion composition comprises: colourless, white or transparent metal oxide particles (A) having a primary particle diameter of 1 nm to 100 nm and a refractive index of from 1.75 to 2.70, a polymer compound (B) having an acid value of 120 mgKOH/g or more, which is represented by the following Formula (1), and a solvent (C): wherein: R1 represents a (m+n)-valent linking group represented by any one of the following Formulae: wherein: L3 represents a trivalent group; T3 represents a single bond or a divalent linking group; and the three T3's may be same or different; L4 represents a tetravalent group; T4 represents a single bond or a divalent linking group, and the four T4's may be the same or different; L5 represents a pentavalent group; T5 represents a single bond or a divalent linking group, and the five T5's may be the same or different; L6 represents a hexavalent group; T6 represents a single bond or a divalent linking group, and the six T6's may be the same or different, R2 represents a single bond or a divalent linking group, A1 represents a monovalent substituent having at least one group selected from the group consisting of an acid group, a urea group, a urethane group, a group having a coordinating oxygen atom, a group having a basic nitrogen atom, a phenol group, an alkyl group, an aryl group, a group having an alkyleneoxy chain, an imide group, an alkyloxycarbonyl group, an alkyl amino carbonyl group, a carboxylate group, a sulfonamide group, a heterocyclic group, an alkoxysilyl group, an epoxy group, an isocyanate group, and a hydroxyl group, n A1's and n R2's may be the same or different, m represents a positive number of 8 or less, n represents 1 to 9, and m+n satisfies 3 to 10, and P1 represents a polymer chain, and m P1,s may be the same or different.

  本文提供了一种具有高折射率和高分散稳定性的分散组合物、一种使用该分散组合物的固化组合物、一种透明薄膜、一种微透镜和一种固态成像装置。 分散组合物包括 无色、白色或透明的金属氧化物颗粒（A），其主颗粒直径为 1 纳米至 100 纳米，折射率为 1.75 至 2.70、 酸值大于或等于 120 mgKOH/g 的聚合物化合物 (B)，如下式 (1) 所示，以及 溶剂 (C)： 其中 R1 代表(m+n)价连接基团，由下式中的任一种表示： 其中 L3 代表三价基团；T3 代表单键或二价连接基团，三个 T3 可以相同或不同； L4 代表四价基团；T4 代表单键或二价连接基团，四个 T4 可以相同或不同；L5 代表五价基团；T5 代表单键或二价连接基团，五个 T5 可以相同或不同； L6 代表六价基团；T6 代表单键或二价连接基团，六个 T6 可以相同或不同、 R2 代表单键或二价连接基团、 A1 代表单价取代基，该取代基至少有一个基团选自以下组别：酸基、脲基、氨基甲酸乙酯基、具有配位氧原子的基团、具有碱性氮原子的基团、酚基、烷基、芳基、醚基、醚烷基、醚醚烷基、醚醚烷基、醚醚烷基、醚醚烷基、醚醚烷基酰亚胺基、烷氧基羰基、烷基氨基羰基、羧酸基、磺酰胺基、杂环基、烷氧基硅基、环氧基、异氰酸酯基和羟基、 n 个 A1 和 n 个 R2 可以相同或不同、 m 代表 8 或以下的正数，n 代表 1 至 9，m+n 满足 3 至 10，以及 P1 代表聚合物链，m P1,s 可以相同或不同。
• MICROLENS COMPRING A TRANSPARENT FILM AND SOLID-STATE IMAGING DEVICE USING THE SAME
  申请人：FUJIFILM Corporation

  公开号：EP3124548B1

  公开（公告）日：2020-12-02
• US7303787B2
  申请人：——

  公开号：US7303787B2

  公开（公告）日：2007-12-04