3,3'-bis(9-phenyl-9H-carbazol-3-yl)biphenyl | 1444173-43-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 3,3'-bis(9-phenyl-9H-carbazol-3-yl)biphenyl
• 英文别名: 3,3'-Bis(9-phenyl-9H-carbazol-3-yl)-1,1'-biphenyl；9-phenyl-3-[3-[3-(9-phenylcarbazol-3-yl)phenyl]phenyl]carbazole
• CAS: 1444173-43-6
• 化学式: C₄₈H₃₂N₂
• 分子量: 636.795
• InChiKey: OIISPAUPFGOFJA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  13
• 重原子数：
  50
• 可旋转键数：
  5
• 环数：
  10.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  9.9
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  N-苯基-3-咔唑硼酸 、 3,3'-二溴联苯 在 四(三苯基膦)钯 、 potassium carbonate 作用下， 以 四氢呋喃 为溶剂， 反应 8.0h， 以85.5%的产率得到3,3'-bis(9-phenyl-9H-carbazol-3-yl)biphenyl
  参考文献：
  名称：

  A simple systematic design of phenylcarbazole derivatives for host materials to high-efficiency phosphorescent organic light-emitting diodes

  摘要：

  通过N-苯基咔唑和联苯之间的Suzuki-Miyaura交叉偶联反应，设计并合成了一系列新型蓝色磷光主体材料，即CTP-1、CTP-2和CTP-3。系统地研究了它们的热、光物理和电化学特性。这些新型主体表现出优异的热稳定性和 113 至 127 °C 的高玻璃化转变温度 (Tg)。这三种材料的三重态能量明显高于(4,4'-双(N-咔唑基)-2,2'-联苯)(CBP, 2.56 eV)和最流行的蓝色磷光材料铱的三重态能量( III) 双[(4,6-二氟苯基)吡啶基-N,C2']吡啶甲酸(FIrpic, 2.65 eV)。这三种新型材料对于蓝色和白色磷光 OLED 具有优异的热性能和电子性能。以 Ir 络合物 FIrpic 作为磷光掺杂剂的蓝色发射器件已被制造出来，并且表现出高效率和低滚降。特别是，当使用 CTP-1 作为主体材料时，在 100 cd m-2 下实现了 40.4 cd A-1 ，在 1000 cd m-2 下实现了 38.2 cd A-1 。在此工作的基础上，还制备了一种全荧光粉白光器件，其电流效率在100 cd m−2 时为64.5 cd A−1，在1000 cd m−2 时电流效率为61.9 cd A−1。

  DOI：

  10.1039/c3tc30410h

文献信息

• A simple systematic design of phenylcarbazole derivatives for host materials to high-efficiency phosphorescent organic light-emitting diodes
  作者：Lin-Song Cui、Shou-Cheng Dong、Yuan Liu、Qian Li、Zuo-Quan Jiang、Liang-Sheng Liao

  DOI：10.1039/c3tc30410h

  日期：——

  A series of novel blue phosphorescent host materials, namely, CTP-1, CTP-2 and CTP-3 have been designed and synthesized through the Suzuki–Miyaura cross-coupling reaction between N-phenylcarbazole and biphenyl. Their thermal, photophysical and electrochemical properties were systematically investigated. These novel hosts show excellent thermal stability and high glass transition temperatures (Tg) ranging from 113 to 127 °C. The triplet energies of these three materials are significantly higher than that of (4,4′-bis(N-carbazolyl)-2,2′-biphenyl) (CBP, 2.56 eV) and that of the most popular blue phosphorescent material iridium(III) bis[(4,6-difluorophenyl)pyridinato-N,C2′] picolinate (FIrpic, 2.65 eV). These three novel materials have superior thermal and electronic properties for blue and white phosphorescent OLEDs. Blue emitting devices with an Ir-complex FIrpic as the phosphorescent dopant have been fabricated and show high efficiency with low roll-off. In particular, 40.4 cd A−1 at 100 cd m−2 and 38.2 cd A−1 at 1000 cd m−2 were achieved when CTP-1 was used as the host material. On the basis of this work, an all-phosphor white device with a current efficiency of 64.5 cd A−1 at 100 cd m−2 and 61.9 cd A−1 at 1000 cd m−2 has also been fabricated.

  通过N-苯基咔唑和联苯之间的Suzuki-Miyaura交叉偶联反应，设计并合成了一系列新型蓝色磷光主体材料，即CTP-1、CTP-2和CTP-3。系统地研究了它们的热、光物理和电化学特性。这些新型主体表现出优异的热稳定性和 113 至 127 °C 的高玻璃化转变温度 (Tg)。这三种材料的三重态能量明显高于(4,4'-双(N-咔唑基)-2,2'-联苯)(CBP, 2.56 eV)和最流行的蓝色磷光材料铱的三重态能量( III) 双[(4,6-二氟苯基)吡啶基-N,C2']吡啶甲酸(FIrpic, 2.65 eV)。这三种新型材料对于蓝色和白色磷光 OLED 具有优异的热性能和电子性能。以 Ir 络合物 FIrpic 作为磷光掺杂剂的蓝色发射器件已被制造出来，并且表现出高效率和低滚降。特别是，当使用 CTP-1 作为主体材料时，在 100 cd m-2 下实现了 40.4 cd A-1 ，在 1000 cd m-2 下实现了 38.2 cd A-1 。在此工作的基础上，还制备了一种全荧光粉白光器件，其电流效率在100 cd m−2 时为64.5 cd A−1，在1000 cd m−2 时电流效率为61.9 cd A−1。
• Organic optoelectronic device and display device
  申请人：SAMSUNG SDI CO., LTD.

  公开号：US10522766B2

  公开（公告）日：2019-12-31

  The present invention relates to an organic photoelectronic device and a display device comprising the organic photoelectronic device, the organic photoelectronic device comprising: an anode; a cathode facing the anode; a light-emitting layer interposed between the anode and cathode; a hole transport layer interposed between the anode and the light-emitting layer; and an auxiliary hole transport layer interposed between the hole transport layer and the light-emitting layer, wherein the hole transport layer comprises a compound represented by Chemical formula I, and the auxiliary hole transport layer comprises a compound represented by Chemical formula II. Chemical formulas I and II are the same as set forth in the description.

  本发明涉及一种有机光电子器件和一种包含该有机光电子器件的显示装置，该有机光电子器件包括一个阳极；一个面向阳极的阴极；一个介于阳极和阴极之间的发光层；一个介于阳极和发光层之间的空穴传输层；以及一个介于空穴传输层和发光层之间的辅助空穴传输层，其中空穴传输层包括由化学式I表示的化合物，而辅助空穴传输层包括由化学式II表示的化合物。化学式 I 和 II 与说明中所述相同。
• Organic electroluminescent compounds and organic electroluminescent device comprising the same
  申请人：ROHM AND HAAS ELECTRONIC MATERIALS KOREA LTD.

  公开号：US11527728B2

  公开（公告）日：2022-12-13

  The present disclosure relates to organic electroluminescent compounds, and a host material, an electron buffer material, an electron transport material and an organic electroluminescent device comprising the same. By using the organic electroluminescent compounds of the present disclosure, the organic electroluminescent device secures fast electron current properties by intermolecular stacking and interaction, and thus, it is possible to provide the organic electroluminescent device having low driving voltage and/or excellent luminous efficiency and/or efficient lifespan properties.

  本公开涉及有机电致发光化合物，以及由其构成的宿主材料、电子缓冲材料、电子传输材料和有机电致发光器件。通过使用本公开的有机电致发光化合物，有机电致发光器件可通过分子间的堆叠和相互作用确保快速电子流特性，从而可提供具有低驱动电压和/或优异发光效率和/或高效寿命特性的有机电致发光器件。
• COMPOSITION FOR ORGANIC OPTOELECTRIC DIODE, ORGANIC OPTOELECTRIC DIODE, AND DISPLAY DEVICE
  申请人：SAMSUNG SDI CO., LTD.

  公开号：US20170104163A1

  公开（公告）日：2017-04-13

  The present invention relates to: a composition for an organic optoelectric diode, containing a first host compound represented by Chemical Formula I and a second host compound represented by Chemical Formula II; an organic optoelectric diode comprising the composition for an organic optoelectric diode; and a display device.
• MULTI-COMPONENT HOST MATERIAL AND AN ORGANIC ELECTROLUMINESCENCE DEVICE COMPRISING THE SAME
  申请人：Rohm and Haas Electronic Materials Korea Ltd.

  公开号：US20170125699A1

  公开（公告）日：2017-05-04

  The present invention relates to a multi-component host material and an organic electroluminescent device comprising the same. By comprising a specific combination of the multi-component host compounds, the organic electroluminescent device according to the present invention can provide high luminous efficiency and excellent lifespan characteristics.