(NE)-N-[1-di(propan-2-yloxy)phosphorylpropylidene]hydroxylamine;trichloropraseodymium | 158176-19-3

• 分子结构分类: 有机化合物 - 有机酸及其衍生物
• 英文名称: (NE)-N-[1-di(propan-2-yloxy)phosphorylpropylidene]hydroxylamine;trichloropraseodymium
• CAS: 158176-19-3
• 化学式: C₂₇H₆₀Cl₃N₃O₁₂P₃Pr
• 分子量: 958.974
• InChiKey: GFIIGEDIFKTIRG-BXHJTSIDSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  氯化镨 、 diisopropyl α-hydroxyiminopropylphosphonate 以 甲醇 为溶剂， 以40%的产率得到(NE)-N-[1-di(propan-2-yloxy)phosphorylpropylidene]hydroxylamine;trichloropraseodymium
  参考文献：
  名称：

  Bligh, S. W. Annie; Choi, Nick; McGrath, Catherine M., Journal of the Chemical Society, Dalton Transactions, 2000, p. 2587 - 2594

  摘要：

  DOI：

文献信息

• Synthesis of the first lanthanide complexes of dialkyl α-hydroxyiminophosphonates; ambivalent ligand bonding in the Pr^IIIand Nd^IIIcomplexes of diisopropyl α-hydroxyiminopropylphosphonate (L¹), [PrL¹₃Cl₃] and [NdL¹₂(NO₃)₃(H₂O)]
  作者：S. W. Annie Bligh、Nick Choi、Harry R. Hudson、Catherine M. McGrath、Mary McPartlin

  DOI：10.1039/dt9940002335

  日期：——

  Lanthanide complexes of dialkyl alpha-hydroxyiminophosphonates (RO)2P(O)C(R')N(OH) (L1-L3), where R = Et or Pr(i) and R' = Me or Et, have been prepared for the first time; the crystal structures of two complexes of L1 (R = Pr(i), R' = Et) have been determined, showing nine-co-ordination geometry in both cases with asymmetric bidentate ligands in [PrL13Cl3] and monodentate bonding in [NdL21(NO3)3(H2O)] demonstrating that the ambivalent nature of the new ligands allow formation of neutral complexes.