3-(2,5-Dioxopyrrol-1-yl)propyl 2,2,5-trimethyl-1,3-dioxane-5-carboxylate | 1032997-27-5

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 3-(2,5-Dioxopyrrol-1-yl)propyl 2,2,5-trimethyl-1,3-dioxane-5-carboxylate
• CAS: 1032997-27-5
• 化学式: C₁₅H₂₁NO₆
• 分子量: 311.335
• InChiKey: NAKWVJRHMMKOJY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.2
• 重原子数：
  22
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  82.1
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  3-(2,5-Dioxopyrrol-1-yl)propyl 2,2,5-trimethyl-1,3-dioxane-5-carboxylate 、 Furan-2-ylmethyl 3,5-bis(phenylmethoxy)benzoate 以 苯 为溶剂， 反应 24.0h， 以96%的产率得到
  参考文献：
  名称：

  Segment Block Dendrimers via Diels−Alder Cycloaddition

  摘要：

  Segment block dendrimers consisting of polyester and polyaryl ether dendrons were synthesized using reagent free Diels-Alder cycloaddition reactions. Three generations of furan functionalized polyaryl ether dendrons were reacted with maleimide functionalized polyester dendrons of the same generation to obtain segment block dendrimers in good yields. The thermoreversible nature of these macromolecules was investigated by subjecting them to elevated temperatures in the presence of anthracene as a scavenger diene.

  DOI：

  10.1021/ol800553t
• 作为产物：
  描述：

  3-[(3aR,4S,7R,7aS)-1,3-dioxo-3a,4,7,7a-tetrahydro-4,7-epoxyisoindol-2-yl]propyl 2,2,5-trimethyl-1,3-dioxane-5-carboxylate 以 甲苯 为溶剂， 以98%的产率得到3-(2,5-Dioxopyrrol-1-yl)propyl 2,2,5-trimethyl-1,3-dioxane-5-carboxylate
  参考文献：
  名称：

  Segment Block Dendrimers via Diels−Alder Cycloaddition

  摘要：

  Segment block dendrimers consisting of polyester and polyaryl ether dendrons were synthesized using reagent free Diels-Alder cycloaddition reactions. Three generations of furan functionalized polyaryl ether dendrons were reacted with maleimide functionalized polyester dendrons of the same generation to obtain segment block dendrimers in good yields. The thermoreversible nature of these macromolecules was investigated by subjecting them to elevated temperatures in the presence of anthracene as a scavenger diene.

  DOI：

  10.1021/ol800553t

文献信息

• Diels-Alder Coupled Proppant Binder Resins
  申请人：Battelle Memorial Institute

  公开号：US20170051200A1

  公开（公告）日：2017-02-23

  Methods and materials for sand control in water injection sites are disclosed. Proppant particles may be coated with some particles coated with a diene and other proppant particles coated with a dienophile that would bind the particles through a Diels-Alder reaction. In some other embodiments, proppant particles may be coated with alternating layers of diene and dienophile that would react through a Diels-Alder reaction. The invention may be advantageous for forming underground structures useful in the extraction of hydrocarbons.