5-bromo-3,3'-biindolinylidene-2,2'-dione | 861592-99-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 5-bromo-3,3'-biindolinylidene-2,2'-dione
• CAS: 861592-99-6
• 化学式: C₁₆H₉BrN₂O₂
• 分子量: 341.164
• InChiKey: OTVAOGSIJKUPDT-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  二氧化碳 、 5-bromo-3,3'-biindolinylidene-2,2'-dione 以 二甲基亚砜 为溶剂， 生成
  参考文献：
  名称：

  Redox-tunable isoindigos for electrochemically mediated carbon capture

  摘要：

  Efficient CO2 separation technologies are essential for mitigating climate change. Compared to traditional thermochemical methods, electrochemically mediated carbon capture using redox-tunable sorbents emerges as a promising alternative due to its versatility and energy efficiency. However, the undesirable linear free-energy relationship between redox potential and CO2 binding affinity in existing chemistry makes it fundamentally challenging to optimise key sorbent properties independently via chemical modifications. Here, we demonstrate a design paradigm for electrochemically mediated carbon capture sorbents, which breaks the undesirable scaling relationship by leveraging intramolecular hydrogen bonding in isoindigo derivatives. The redox potentials of isoindigos can be anodically shifted by >350 mV to impart sorbents with high oxygen stability without compromising CO2 binding, culminating in a system with minimised parasitic reactions. With the synthetic space presented, our effort provides a generalisable strategy to finetune interactions between redox-active organic molecules and CO2, addressing a longstanding challenge in developing effective carbon capture methods driven by non-conventional stimuli.

  DOI：

  10.1038/s41467-024-45410-z
• 作为产物：
  描述：

  2-吲哚酮 、 5-溴靛红 在 Sulfonic-acid-functionalized nanoporous silica 作用下， 反应 0.2h， 以60%的产率得到5-bromo-3,3'-biindolinylidene-2,2'-dione
  参考文献：
  名称：

  Efficient green synthesis of isoindigo derivatives using sulfonic-acid-functionalized nanoporous silica (SBA-Pr-SO3H) catalyst and study of their antimicrobial properties

  摘要：

  已开发出一种高效的绿色缩合反应，使用孔径为6纳米的SBA-Pr-SO3H作为异质纳米孔酸催化剂，在无溶剂条件下合成trans-异苯骈二氮杂环衍生物。异苯骈二氮杂环衍生物在染料、药物、有机太阳能电池和半导体存储等多个工业领域有广泛应用。这些化合物的抗菌活性也进行了测试。

  DOI：

  10.1007/s11164-012-0909-y