Pinacolyl methyl phosphonate | 687-02-5

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: Pinacolyl methyl phosphonate
• 英文别名: 3-[Methoxy(oxido)phosphaniumyl]oxy-2,2-dimethylbutane
• CAS: 687-02-5
• 化学式: C₇H₁₇O₃P
• 分子量: 180.184
• InChiKey: BCMYDRYDGRIQPF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.6
• 重原子数：
  11
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  41.5
• 氢给体数：
  0
• 氢受体数：
  3

文献信息

• Process for preparing vinyl substituted beta-diketones
  申请人：Southard E. Glen

  公开号：US20060069288A1

  公开（公告）日：2006-03-30

  A process for preparing vinyl substituted beta-diketones includes reacting a halogen-containing beta-diketone with an olefin in a reaction zone under Heck coupling reaction conditions in the presence of a catalyst, a base, and an organic phosphine to provide a vinyl substituted beta-diketone product.

  制备乙烯基取代的β-二酮的方法包括在反应区域中，在存在催化剂、碱和有机膦的条件下，将含卤素的β-二酮与烯烃进行 Heck 偶联反应，从而得到乙烯基取代的β-二酮产物。
• EP1733211A4
  申请人：——

  公开号：EP1733211A4

  公开（公告）日：2007-05-30
• PROCESSABLE MOLECULARLY IMPRINTED POLYMERS
  申请人：THE JOHNS-HOPKINS UNIVERSITY

  公开号：EP1733211A1

  公开（公告）日：2006-12-20
• Chemical sensors featuring dual-sensing motifs
  申请人：Booksh S. Karl

  公开号：US20070031292A1

  公开（公告）日：2007-02-08

  Apparatus and methods featuring a sensor ( 10 ) having dual-sensing motifs. The sensor ( 10 ) includes an entrant medium ( 12 ), a thin metal film layer ( 14 ), sensing elements ( 16 ), and a fluorescent molecule ( 18 ) associated with the sensing elements ( 16 ). A target molecule ( 20 ) is captured by the sensing elements ( 16 ), and Surface Plasmon Resonance (SRP) and fluorescent detection are employed. The apparatus and methods were tested for the detection of Pinacolyl methylphosphanate (PMP), a simulant for nerve agent Soman.
• Processable molecularly imprinted polymers
  申请人：Southard E. Glen

  公开号：US20070197746A1

  公开（公告）日：2007-08-23

  A process is provided herein for preparing molecularly imprinted polymers for detecting a target analyte by Reversible Addition Fragmentation Chain Transfer (RAFT). The process includes providing a complex having the formula L?3#191M wherein L is a β-diketone ligand containing a chain transfer moiety and L?3#191 can be the same or different ligands, and M is a lanthanide element; reacting the complex with the target analyte to provide an adduct containing the target analyte; co-polymerizing the adduct with a monomer and cross-linking agent to provide a polymer; and, removing the target analyte from the polymer to provide the molecularly imprinted polymer.