2,2'-Diphenyl-5,5'-dibenzoxazolylsulfon | 17423-70-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: 2,2'-Diphenyl-5,5'-dibenzoxazolylsulfon
• 英文别名: 2,2'-diphenyl-5,5'-sulfonyl-bis-benzooxazole；2-Phenyl-5-[(2-phenyl-1,3-benzoxazol-5-yl)sulfonyl]-1,3-benzoxazole
• CAS: 17423-70-0
• 化学式: C₂₆H₁₆N₂O₄S
• 分子量: 452.49
• InChiKey: NNADIPSFFTUYKG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.7
• 重原子数：
  33
• 可旋转键数：
  4
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  94.6
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  bis-(4-benzoyloxy-3-nitro-phenyl) sulfone 在 盐酸 、 铁粉 作用下， 生成 2,2'-Diphenyl-5,5'-dibenzoxazolylsulfon
  参考文献：
  名称：

  Synthesis of aromatic bisbenzoxazoles by reductive heterocyclization

  摘要：

  DOI：

  10.1007/bf00514730

文献信息

• Voznesenskaya,N.N.; Braz,G.I., Journal of Organic Chemistry USSR (English Translation), 1971, vol. 7, p. 1534 - 1535
  作者：Voznesenskaya,N.N.、Braz,G.I.

  DOI：——

  日期：——
• KORSHAK V. V.; PYCAHOB A. L.; TUGUSHI D. S.; DZHAPARIDZE Z. SH.; ANDRONIK+, XIMIYA GETEROTSIKL. SOEDIN. 1979, HO 12, 1620-1623
  作者：KORSHAK V. V.、 PYCAHOB A. L.、 TUGUSHI D. S.、 DZHAPARIDZE Z. SH.、 ANDRONIK+

  DOI：——

  日期：——
• PARTICLE-DISPERSED POLYIMIDE PRECURSOR SOLUTION, METHOD FOR PRODUCING POROUS POLYIMIDE FILM, AND POROUS POLYIMIDE FILM
  申请人：FUJIFILM Business Innovation Corp.

  公开号：US20220119596A1

  公开（公告）日：2022-04-21

  A particle-dispersed polyimide precursor solution contains a polyimide precursor having a unit represented by the following formula (I), particles, and a solvent, in which the particle-dispersed polyimide precursor solution satisfies both the following conditions (1) and (2), (in the formula (I), A represents a tetravalent organic group, and B represents a divalent organic group represented by any of the following formulas (B1) to (B4)), (in the formulas (B1) to (B4), Ar 1 , Ar 10 , and Ar 11 each independently represent a trivalent aromatic group which may have a substituent, Ar 2 , Ar 4 , Ar 5 , Ar 7 and Ar 8 each independently represent a divalent aromatic group which may have a substituent, Ar 3 and Ar 6 each independently represent a tetravalent aromatic group which may have a substituent or a group represented by the following formula (II), Ar 9 represents a divalent aromatic group which may have a substituent or a group represented by the following formula (III), X 1 to X 7 each independently represent NRa, O, or S, Ra represents a hydrogen atom, an alkyl group which may have a substituent, or an aryl group, and * represents a bonding site with an adjacent linking group), and (in the formulas (II) and (III), Ar 12 and Ar 13 each independently represent a trivalent aromatic group which may have a substituent, Ar 14 and Ar 15 each independently represent a divalent aromatic group which may have a substituent, Y and Z each independently represent O, S, S(═O) 2 , or CRbRc, Rb and Rc each independently represent a hydrogen atom, an alkyl group which may have a substituent, or an aryl group, and * represents a bonding site with an adjacent linking group), Condition (1): a total content of the groups represented by the formulas (B1) to (B4) is 1% by mass or more and 40% by mass or less with respect to a total amount of the polyimide precursor, and Condition (2): a content of the particles is 5% by mass or more and 90% by mass or less with respect to a total content of the polyimide precursor and the particles.