2-Diethylphosphoryl-1-phenylethanone | 67152-27-6

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 2-Diethylphosphoryl-1-phenylethanone
• CAS: 67152-27-6
• 化学式: C₁₂H₁₇O₂P
• 分子量: 224.24
• InChiKey: NXJXJSYDSVHDCL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.5
• 重原子数：
  15
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.42
• 拓扑面积：
  34.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  diethylphosphine oxide 、 alpha-氯乙酰苯 在 potassium hydroxide 作用下， 以68%的产率得到2-Diethylphosphoryl-1-phenylethanone
  参考文献：
  名称：

  Synthesis of β-carbonylphosphine oxides and phenyl-substituted ethylenediphosphine oxides. study of their complexing with alkali metals cations

  摘要：

  The synthesis of some beta-carbonylphosphine oxides and phenyl-substituted ethylenediphosphine oxides was carried out. Their complexing with alkali metals cations was studied. Compounds obtained were shown to possess clearly expressed Li/Na selectivity.

  DOI：

  10.1134/s1070363209100065

文献信息

• Synthesis of β-carbonylphosphine oxides and phenyl-substituted ethylenediphosphine oxides. study of their complexing with alkali metals cations
  作者：A. E. Antoshin、Yu. N. Reikhov、K. V. Tugushov、I. V. Rybal’chenko、V. F. Taranchenko、S. A. Lermontov、A. N. Malkova

  DOI：10.1134/s1070363209100065

  日期：2009.10

  The synthesis of some beta-carbonylphosphine oxides and phenyl-substituted ethylenediphosphine oxides was carried out. Their complexing with alkali metals cations was studied. Compounds obtained were shown to possess clearly expressed Li/Na selectivity.