1-ethyl-3-methylimidazolium bromide - AlCl3 | 869484-23-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: 1-ethyl-3-methylimidazolium bromide - AlCl3
• 英文别名: Bromo(trichloro)alumanuide;1-ethyl-3-methylimidazol-3-ium；bromo(trichloro)alumanuide;1-ethyl-3-methylimidazol-3-ium
• CAS: 869484-23-1
• 化学式: AlCl₃*Br*C₆H₁₁N₂
• 分子量: 324.411
• InChiKey: UXYIJZQQHOVYSP-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  2.87
• 重原子数：
  13
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  8.8
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  亚锑氢化物 、 碲化氢 、 三氯化铝 、 1-ethyl-3-methylimidazolium bromide - AlCl3 以 neat (no solvent) 为溶剂， 生成
  参考文献：
  名称：

  Synthesis in Ionic Liquids: [Bi₂Te₂Br](AlCl₄), a Direct Gap Semiconductor with a Cationic Framework

  摘要：

  The Lewis acidic ionic liquid EMIMBr-AlCl3 (EMIM = 1-ethyl-3-methylimidazolium) allows a novel synthetic route to the semiconducting layered metal chalcogenides halide [Bi2Te2Br](AlCl4) and its Sb analogue. [Bi2Te2Br](AlCl4) is a direct band gap, strongly anisotropic semiconductor and consists of cationic infinite layers of [Bi2Te2Br](+) and [AlCl4](-) anions inserted between the layers.

  DOI：

  10.1021/ja107483g

文献信息

• Synthesis in Ionic Liquids: [Bi₂Te₂Br](AlCl₄), a Direct Gap Semiconductor with a Cationic Framework
  作者：Kanishka Biswas、Qichun Zhang、In Chung、Jung-Hwan Song、John Androulakis、Arthur J. Freeman、Mercouri G. Kanatzidis

  DOI：10.1021/ja107483g

  日期：2010.10.27

  The Lewis acidic ionic liquid EMIMBr-AlCl3 (EMIM = 1-ethyl-3-methylimidazolium) allows a novel synthetic route to the semiconducting layered metal chalcogenides halide [Bi2Te2Br](AlCl4) and its Sb analogue. [Bi2Te2Br](AlCl4) is a direct band gap, strongly anisotropic semiconductor and consists of cationic infinite layers of [Bi2Te2Br](+) and [AlCl4](-) anions inserted between the layers.