bis (N-(2-methylpyridine)-2-aminomethylbenzoate) manganese(II) | 688004-62-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: bis (N-(2-methylpyridine)-2-aminomethylbenzoate) manganese(II)
• CAS: 688004-62-8
• 化学式: C₂₈H₂₆MnN₄O₄
• 分子量: 537.477
• InChiKey: WCDKZUXVVBWXGF-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  manganese(II) perchlorate hexahydrate 、 2-[(吡啶-2-基甲基氨基)甲基]苯甲酸 在 NaOH 作用下， 以 乙腈 为溶剂， 以0%的产率得到bis (N-(2-methylpyridine)-2-aminomethylbenzoate) manganese(II)
  参考文献：
  名称：

  Synthesis, structural characterization and redox properties of copper(II) and manganese(II) complexes containing tridentate (N-(2-methylpyridine)-2-aminomethyl benzoate) ligand

  摘要：

  Two new complexes, [Cu(mamba)(2)] and [Mn(mamba)(2)] (mamba(-), N-(2-methylpyridine)-2-aminomethyl benzoate) were synthesized and characterized by X-ray crystallography. Whereas the [Cu(mamba)(2)] complex crystallizes in a monoclinic P2(1)/c space group, the [Mn(mamba)(2)] complex crystallizes in a triclinic P (l) over bar space group. The nature of the metal ion greatly influences the lattices and the molecular structures of the compounds. In the crystal lattice of the copper complex are four cocrystallized methanol solvent, which are all involved in building six strong H-bonds with the complex. However, the lattice for the manganese complex contain only one cocrystallized methanol, along with one NaClO4, that is also involved in making one H-bond with the [Mn(mamba)(2)] unit. Nevertheless, the sodium ion is coordinated to the ClO4, the methanol and two [Mn(mamba)(2)] to form a stable extended chain metal complex. Electrochemical studies indicated that both complexes undergo quasi reversible one electron reduction in acetonitrile. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2003.10.025