bis[di(hydroxymethyl)phosphinato]diaquacobalt(II) | 909791-56-6

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: bis[di(hydroxymethyl)phosphinato]diaquacobalt(II)
• CAS: 909791-56-6
• 化学式: C₄H₁₆CoO₁₀P₂
• 分子量: 345.106
• InChiKey: XWWAMWKKLFDJSM-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  二(羟基甲基)次磷酸 、 cobalt(II) carbonate 以 水 为溶剂， 生成 bis[di(hydroxymethyl)phosphinato]diaquacobalt(II)
  参考文献：
  名称：

  Bis[di(hydroxymethyl)phosphinato]diaquacobalt(II), [Co(H2O)2{(HOCH2)2PO2}2]: Synthesis, properties, and crystal structure

  摘要：

  The synthesis and some properties of the Co(II) complex with di(hydroxymethyl)phosphinic acid (HL) of the composition CoL2 center dot 2H(2)O are described. X-ray powder diffraction analysis confirmed the phase homogeneity of the polycrystalline sample. The crystal structure is determined by X-ray diffraction method. The Co atom is located in the center of octahedron formed by the O atoms of two ligands L and of two water molecules. The ligand L performs bidentate-chelate function and is bonded to the Co atom through the O atoms of the phosphinate group and of one alcohol group.

  DOI：

  10.1134/s1070328406020035