[1,1'-biphenyl]-2,2'-diylbis((4-(diphenylamino)phenyl)methanone) | 1432623-59-0

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二芳基庚烷
• 英文名称: [1,1'-biphenyl]-2,2'-diylbis((4-(diphenylamino)phenyl)methanone)
• 英文别名: [2-[2-[4-(N-phenylanilino)benzoyl]phenyl]phenyl]-[4-(N-phenylanilino)phenyl]methanone
• CAS: 1432623-59-0
• 化学式: C₅₀H₃₆N₂O₂
• 分子量: 696.848
• InChiKey: WKBXPYYWEYHJDT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  12.7
• 重原子数：
  54
• 可旋转键数：
  11
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  40.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  phenyl 4-(diphenylamino)benzoate 在 1,1'-双(二苯基膦)二茂铁 、 三氟甲磺酸 、 potassium carbonate 、 三乙胺 、 联硼酸频那醇酯 、 palladium dichloride 作用下， 以 二氯甲烷 、 二甲基亚砜 为溶剂， 反应 43.0h， 生成 [1,1'-biphenyl]-2,2'-diylbis((4-(diphenylamino)phenyl)methanone)
  参考文献：
  名称：

  Paraphenylene dimers with diphenylamine donor groups: synthesis and photophysics

  摘要：

  A novel paraphenylene dimer (D696) with electron donating diphenylamine side chain groups has been prepared. Optical absorption measurements were theoretically and experimentally determined showing a red shift in the absortivity relative to dialkylamine functionalized benzophenone dimers. The fluorescence of D696 was quenched in a concentration dependent manner in the presence of reduced graphene oxide (RGO). (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2013.03.141

文献信息

• Paraphenylene dimers with diphenylamine donor groups: synthesis and photophysics
  作者：Khoa Le、Lokendra B. Chand、Colette Griffin、Alfred L. Williams、Darlene K. Taylor

  DOI：10.1016/j.tetlet.2013.03.141

  日期：2013.6

  A novel paraphenylene dimer (D696) with electron donating diphenylamine side chain groups has been prepared. Optical absorption measurements were theoretically and experimentally determined showing a red shift in the absortivity relative to dialkylamine functionalized benzophenone dimers. The fluorescence of D696 was quenched in a concentration dependent manner in the presence of reduced graphene oxide (RGO). (C) 2013 Elsevier Ltd. All rights reserved.